Definitions Flashcards

1
Q

State what is meant by the term partition coefficient. /1

A

it is the ratio of concentration of solutes in two solvents

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2
Q

State what is meant by the term co-ordination number. /1

A

number of dative bonds formed with metal ion

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3
Q

Define the term transition element./1

A

element forms stable ions with partially filled d subshell

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4
Q

Define the term monodentate ligand. /1

A

Ligand donates one pair of electron to central atom to form 1 dative bond

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5
Q

Define the term standard electrode potential /2

A

it is the voltage of an electrode compared to SHE cell under standard conditions

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6
Q

Define the term buffer solution. /2

A

a solution which resists a change in pH when a small amount of

acid or an alkali is added to the solution

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7
Q

Define enthalpy change of solution. /1

A

enthalpy change when one mole of a solute is dissolved in water to form infinitely dilute solution

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8
Q

State what is meant by bidentate ligand. /2

A

species with two lone pairs of electrons

that form dative bond to central metal

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9
Q

State what is meant by isoelectric point. /1

A

pH at which a molecule has no overall charge

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10
Q

Define monodentate ligand. /2

A

ligand donates one lone pair to central metal to form one dative bond

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11
Q

Define enantiomers./1

A

rotate the plane of polarised light in opposite direction

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12
Q

Define the term complex ion. /1

A

molecule formed by a central metal bonded to one or more ligands

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13
Q

Define stability constant Kstab. /1

A

the equilibrium constant for the formation of the complex ion in a solvent

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14
Q

Define first electron affinity. /2

A

energy change when one mole of electrons is gained by one mole of gaseous atoms

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15
Q

Explain what is meant by optically active. /1

A

a substance that is able to ROTATE the plane of polarised light in opposite directions

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16
Q

Explain what is meant by a heterogeneous catalyst. /1

A

catalysts and reactants are in different phase

17
Q

Describe what is meant by racemic mixture? /1

A

a mixture containing equal amounts of each optical isomer