definitions Flashcards
chemical bonding
The mutual interaction between atoms resulting from the attraction and repulsion between their nuclei and valence electrons.
bond energy
The energy needed to break chemical bonds to form neutral atoms.
bond length
The average distance between the nuclei of two bonded atoms.
ionic bonding
The electrostatic interaction between cations and anions that involves the
transfer of electrons and forms a three-dimensional lattice structure.
covalent bonding
The electrostatic interaction that involves the sharing of electrons between atoms to form molecules.
dative covalent bonding
A bond that involves the sharing of an electron pair between atoms where both electrons are donated by one of the two atoms.
molecule
It is a neutral group of two or more atoms which are bonded together
sufficiently strongly to act as a unit in chemical reactions.
bonding pair (shared pair)
It is the pair of electrons that is shared between two atoms in a covalent bond.
lone pair
It is a pair of electrons in the valence shell of an atom that is not shared with another atom.
electronegativity
It is a measure of the tendency of an atom to attract a shared pair of electrons towards itself.
polar covalent bond
A bond that is formed as a result of the unequal sharing of electrons between two atoms.
non-polar (pure) covalent bond
The bond that is formed as a result of an equal sharing of electrons between two atoms.
the heat of the reaction
is the energy absorbed or released in a chemical reaction?
exothermic reactions
are reactions that release energy.
endothermic reactions
reactions that absorb energy
reversible reaction
a reaction where products can be converted back into reactants.
activation energy
the minimum energy needed for a reaction to take place.
activated complex
is the unstable transition state from reactants to products in a chemical reaction.
intermolecular forces
are the forces of attraction or repulsion between molecules.
intramolecular forces
or interatomic forces are the forces between atoms or ‘inside’ molecules which keep atoms together.
dipole dipole forces
are the forces between polar molecules.
induced dipole forces
or London forces are the forces between non–polar molecules.
hydrogen bonds
are the forces between molecules in which a hydrogen atom that is covalently
bonded to a small, highly electronegative atom is attracted to a lone pair of
electrons on an atom in a neighbouring molecule.
boiling point
is the constant temperature at which the vapour pressure of a substance equals atmospheric pressure.
melting point
is the temperature at which the solid and liquid phases of a substance are at equilibrium.
vapour pressure
is the pressure exerted by a vapour at equilibrium with its liquid in a closed
system.
forces of cohesion
are forces of attraction between molecules of the same substance.
forces of adhesion
are forces of attraction between molecules of different substances.
capillarity
is the tendency of a liquid to be elevated or depressed in a narrow tube as a result of surface tension.