definitions Flashcards
base peak
Peak of greatest abundance in a mass spectrum.
molecular ion peak
A peak produced by an ion formed by the removal of one
electron from a molecule.
m+1 peak
A peak produced by a molecular ion with an increased mass
due to the presence of one carbon-13 atom.
fragmentation ion
A positively charged ion produced when the molecular ion
breaks apart.
L RES MR
A spectrum which does not show the spin-spin splitting
pattern.
high res mr
A spectrum which does show the spin-spin splitting pattern.
doublet
A signal which appears as a pair of lines of equal intensity
triplet
A signal which appears as three lines in the approximate
intensity ratio (1:2:1)
quartet
A signal which appears as four lines in the approximate
intensity ratio (1:3:3:1)
transition metal
An element which forms at least one stable ion with a
partially filled d-subshell.
complex
A central metal atom or ion with ligands bonded by
co-ordinate bonds.
ligand
An ion or molecule with a lone pair of electrons which forms a
co-ordinate bond with a central metal atom or ion in a
complex.
co ord number
The number of co-ordinate bonds to a central metal atom or
ion in a complex.
monodentate
A ligand which uses only one lone pair of electrons to form a
co-ordinate bond with a central metal atom or ion in a
complex.
standard electrode potential
The potential difference measured when a half-cell is connected
to the standard hydrogen electrode under standard conditions.