Definitions Flashcards
lattice
infinite set of points defined by integer sums of a set of linearly independent primitive lattice vectors = infinite discrete set of vectors where addition/subtraction of any 2 vectors in the set gives a 3rd vector in the set
what are lattice points described as?
R = n1a1 + n2a2 + n3a3
what’s an important property of lattices that defines them?
the environment of any given point in the lattice is equivalent to the environment of any other given point
unit cell
region of space such that when many identical unit cells are stacked together, it completely fills all of space and reconstructs the full structure
primitive unit cell
smallest possible unit cell = unit cell containing exactly 1 lattice point
why do we sometimes choose a conventional unit cell?
easier to work with than a primitive unit cell
Wigner-Seitz unit cell
for a given lattice point, it’s constructed by considering all points in space which are closer to that given lattice point than to any other lattice point
basis
description of objects in the unit cell with respect to the reference lattice point in the unit cell
reciprocal lattice condition
given a direct lattice of points R, a point G is a point in reciprocal lattice if e^(iG.R) = 1 for all points R of direct lattice
property of primitive lattice vectors of the reciprocal lattice
ai.bj = 2πδij
lattice plane
= crystal plane = plane containing at least 3 non-collinear points of a lattice
family of lattice planes
infinite set of equally separated parallel lattice planes - taken together, they contain all points of the lattice
spacing between lattice planes
d = 2π/Gmin. Gmin = min length reciprocal lattice vector in this normal direction
Miller indices
notation for describing lattice planes (can be negative)
first Brillouin zone
all k points which are closer to 0 than to any other reciprocal lattice point
second Brillouin zone
all k points where point 0 is the second closest reciprocal lattice point to that point
Brillouin zone
any primitive unit cell of the reciprocal latice
structure factor
accounts for scattering power of basis atoms within conventional unit cell