Definitions Flashcards
Standard enthalpy of formation
Enthalpy change when one mole of a compound is formed from its elements with all substances in standard states under standard conditions
Standard enthalpy of combustion
Enthalpy change for one mole of a substance is burned completely in excess oxygen under standard conditions with all substances in standard states
Enthalpy of neutralisation
Enthalpy change for one mole of water is formed in a reaction between an acid and alkali under standard conditions
1st Ionisation enthalpy
Enthalpy change when one mole of gaseous atoms each lose an electron to form one mole of gaseous 1+ ions
Electron affinity
Enthalpy change when one mole of gaseous atoms each gain an electron to form one mole of gaseous 1- ions
Enthalpy of atomisation
Enthalpy change when one mole of gaseous atoms is produced from an element in its standard state
Enthalpy of solution
Enthalpy change when one mole of an ionic solid dissolves in water to form a solution of infinite dilution
Enthalpy of hydration
Enthalpy change when one mole of gaseous ions dissolves in water (becomes hydrated)
Bond dissociation enthalpy
Enthalpy change when one mole of covalent bonds is broken in the gaseous state
Lattice enthalpy of formation
Enthalpy change when one mole of an ionic solid is formed from its constituent ions in the gas phase
Lattice enthalpy of dissociation
Enthalpy change when one mole of an ionic solid is broken up into its constituent ions in the gas phase
Enthalpy of vaporisation
Enthalpy change when one mole of a liquid is turned into gas
Enthalpy of fusion
Enthalpy change when one mole of a solid is turned into a liquid
Standard conditions
100kPa and a given temp (ie: 298K). Represented by theta
Standard states
State substance is in when under standard conditions