Definitions Flashcards

1
Q

Standard enthalpy of formation

A

Enthalpy change when one mole of a compound is formed from its elements with all substances in standard states under standard conditions

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2
Q

Standard enthalpy of combustion

A

Enthalpy change for one mole of a substance is burned completely in excess oxygen under standard conditions with all substances in standard states

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3
Q

Enthalpy of neutralisation

A

Enthalpy change for one mole of water is formed in a reaction between an acid and alkali under standard conditions

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4
Q

1st Ionisation enthalpy

A

Enthalpy change when one mole of gaseous atoms each lose an electron to form one mole of gaseous 1+ ions

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5
Q

Electron affinity

A

Enthalpy change when one mole of gaseous atoms each gain an electron to form one mole of gaseous 1- ions

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6
Q

Enthalpy of atomisation

A

Enthalpy change when one mole of gaseous atoms is produced from an element in its standard state

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7
Q

Enthalpy of solution

A

Enthalpy change when one mole of an ionic solid dissolves in water to form a solution of infinite dilution

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8
Q

Enthalpy of hydration

A

Enthalpy change when one mole of gaseous ions dissolves in water (becomes hydrated)

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9
Q

Bond dissociation enthalpy

A

Enthalpy change when one mole of covalent bonds is broken in the gaseous state

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10
Q

Lattice enthalpy of formation

A

Enthalpy change when one mole of an ionic solid is formed from its constituent ions in the gas phase

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11
Q

Lattice enthalpy of dissociation

A

Enthalpy change when one mole of an ionic solid is broken up into its constituent ions in the gas phase

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12
Q

Enthalpy of vaporisation

A

Enthalpy change when one mole of a liquid is turned into gas

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13
Q

Enthalpy of fusion

A

Enthalpy change when one mole of a solid is turned into a liquid

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14
Q

Standard conditions

A

100kPa and a given temp (ie: 298K). Represented by theta

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15
Q

Standard states

A

State substance is in when under standard conditions

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16
Q

Enthalpy change

A

Heat energy change during a reaction under constant pressure

17
Q

Why might mean bond enthalpy be inaccurate

A

Data quoted is not specific to the bond as it’s from a range of compounds