Definitions Flashcards
Pollution
the introduction by man into the environment of substances or energy liable to cause hazard to human health, harm to living resources and ecological systems, damage to structure or amenity or interference with legitimate use of the environment
anthropogenic
pollution arising from human activities
biogenic
pollution from natural origins- such as animals or plants
wildfire
uncontrolled fire in an area of combustible vegetation that occurs in the countryside area
quasi-natural hazards
hazards that are caused by anthropogenic activities as well as being natural features.
such as volcanoes, earthquakes, and tropical storms.
relative humidity
ratio of actual to saturated vapour pressure, often expressed as a percentage
mixing ratio in atmospheric chemistry
ratio of the amount of the substance of concern in a given volume to the amount of all constituents of air in that volume.
relationship between volume mixing ratio and mass per unit volume
ugm-3 - ppb x molecular weight/molar volume (litres).
22.4= volume in litres occupied by one mole of gas at one atmosphere of pressure
T= absolute temperature (k)
P= atmospheric pressure (MB or Torr)
molar volume equation
22.4 x T/273 x 1013/P
22.4= volume in litres occupied by one mole of gas at one atmosphere of pressure T= absolute temperature (k) P= atmospheric pressure (MB or Torr)
primary pollutants
those which are emitted directly into the atmosphere.
example: CO comes directly from the incomplete combustion of fossil fuels in motor vehicles
secondary pollutants
formed in the air as a result of chemical reactions with other pollutants and atmospheric gases
natural pollutants
air pollutants from natural processes- such as volcanic eruptions, sand storms, lightning and forest fires
examples of man-made pollutants
coal mining, domestic and industrial solvent use, natural gas leakage
point sources
large, geographically-concentration emitters whose emission rates are large enough to be significant by themselves even if no other sources are present- such as coal fired power stations
area sources
collections of small geographically, dispersed emitters that are not significant individually, but are important collectively, such as residential and commercial areas.
line sources
a collection of relatively small sources that are distributed roughly uniformly along a line, such as a motorway or industries along a major river, a main road, or railway line.
emissions inventories
systematic compilation of detailed information on pollutant emissions in a given area
emission factors
is a number that represents the relationship between the mass of a given pollutant emitted from a particular source and the given amount of raw material processes.
activity rate x emission factor = emission rate
acute symptoms
immediate symptoms
eg- eye, nose and throat irritation, aching lungs, wheezeing, coughing, nausea.
chronic effects
long term
examples: heart disease, chronic obstructive pulmonary disease, genotoxic effects (leukaemia, lymphonas, lung cancer)
ODS
ozone depleting substances
CFCs
chloroflurocarbons
HCFCs
hydrochlorofluorocarbons
sick building syndrome
of occupants of building expereince various aliments and illnesses characterised by headaches, respiratory problems etc- the building is described as having sick building syndrome.
emissions map
emissions of pollutants given in the form of UK maps. these maps give emissions of various pollutants on a 1x1km resolution.
data warehouse
emissions data is made available in numerous formats through a database. this allows extraction of overview summary tables.
time-series plot
a set of ordered observations taken over time which may be plotted as a graph and analysed for the identification of trends and other factors such as daily or seasonal variations
DAs
Devolved Administrations
emission standards
many national and international authorities issue legislative standards that aim to control the emissions of pollutants from source.
air quality standard
a pollutant concentration that is regarded as acceptable - the concentration of a pollutant in the air that is unlikely to cause any significant detrimental effects on human health or the environment.
limit values in air quality standards
mandatory values and should not be exceeded anywhere, being designed to improve the protection of human health
guide values in air quality standards
intended to serve as long-term precautions for health and the environment.
ambient concentration
the normal level of concentration of pollutant on an average day
devolved administrations
power generation dominating and emissions falling rapidly across the time series
VOC
volatile organic compounds
NMVOC
non-methane volatile organic compounds
PAHs
Polyaromatic hydrocarbons, usually particulate-associated
THC
total hydrocarbons
EPAQS
Expert Panel in Air Quality Standards
aldehydes
general formula of RHC=O, with R being an organic stem. they are volatile and present as gases in urban air.
free radical
an atom or group of atoms possessing an odd (unpaired) electron.
ketone
C=O functional group, but different formular with 2 R groups.
alcohols
-OH functional group
heterocycles
organic compounds that contain rings possessing atoms other than carbon and hydrogen.
TOMPS
toxic organic micropollutants
PAN
peroxyacetyl nitrate
particles
aggregations of matter (either solid or liquid), which are larger than individual molecules. the size is expressed as diameter.
SPM
suspended particulate matter
suspended particulate matter
a general term embracing all airborne particles
Aerosol
a suspension of particles in a gas. these can be liquid or solid. they are classified by regional type - eg, marine, urban, desert etc.
PM10
particles that are able to pass through a size selective inlet with a 50% efficiency cut off at 10um aerodynamic diameter.
aerodynamic diameter
unit density spherical particles with the same aerodynamic properties
inhalable particles
particles which can enter the human nose or mouth during normal breathing
respirable particles
those inhalable particles that are able to penetrate to the unciliated regions of the deep lung (alveolar region).
smoke
suspended particulate air pollutant with a diameter of less than 15 um, arising from the incomplete combustion of fossil fuels
two types- dark smoke and gravimetric smoke
dark smoke
measures by reflectance
gravimetric smoke (or TSP)
measured in terms of mass
AD
aerodynamic diameter
nuclei mode
particles formed by the condensation from the gaseous phase, as a result of recent combustion. short lifetime
accumulation mode
particles formed by the coagulation of particles from the nuclei mode and condensation on existing material. have a lifetime of days
coarse particle mode
generally produced by mechanical processes, such as comminution. they are few in number and have a very short atmospheric lifetimes.
dry deposition
this is the continuous transfer of particles (and gases) by impaction, sedimentation (removal by gravity) and Brownian motion
Brownian motion
erratic movement due to the movement of air molecules
deposition velocity
calculates the rate of dry deposition.
wet deposition
transport of particles and gases to the earth;s surface in aqueous form.
rain-in or in-cloud scavenging
the main route for wet deposition, particles are included in the developing water droplet in a cloud
wash-out, or below-cloud scavenging
less efficient removal process whereby particles are scavenged by precipitating droplets
primary particulate matter
that whcih is emitted directly to the atmosphere from a combustion source
coarse particles
arise from the re-suspension of soils and dist, sea spray and construction activity
secondary particulate matter
forms within the atmosphere from the condensation of vapours or by the chemcial reaction of gases of natural or anthropogenic origin
PEC
particulate elemental carbon
particulate elemental carbon
derived from combustion processes, it is the black component of smoke responsible for the soiling of materials and the absorption of light.
soil-derived minerals
due to the re-suspension of the earth’s surface.
particle mass concentrations
the mass of particles per unit volume of air
particle number density
the number of particles per unit volume of air
respiratory particles
those finer than 10um
LA-IPPC
Local Authority Integrated Pollution Prevention and Control
BAT
best available techniques
network design
design parameters for monitoring networks
quality assurance and quality control
procedures and systems applied to activities within a programme such that the overall programme meets defined and appropriate standards with a stated level of confidence.
automatic networks
produce hourly pollutant concentrations, with the data being collected remotely from the monitoring site via a modern link
non-automatic networks
measures pollutants less frequently. daily, weekly or monthly. samples are collected by some physical means. the samples are then subjected to chemcial analysis before the final pollutants concentrations are determined
hot-spots
source monitoring, focusing only on areas with high pollution levels
source monitoring
focusing just on hotspots
background or baseline monitoring
designed to assess the exposure of the general population or ecosystem to key pollutants
data validation
rapid initial screening of the data to identify or remove data that is clearly incorrect
data ratification
performed by independent QA units
UKEAP
Eutrophying and acidifying pollutants
biological monitoring
bacteriological measurements
physical measurements
measurement of airbourne particle concentrations using filter papers or light obscuration
chemical analysis
spectroscopic methods
DOAS
Differential Optical Absorption Spectroscopy