Definition Flashcards

1
Q

Molecular orbital

A

result form interaction of atomic orbital of bonding atom

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2
Q

isotope

A

atoms who have the same atomic number but different mass number

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3
Q

covalent bond

A

a chemical bond which involved the sharing of electron pairs between atoms

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4
Q

delocalized bond

A

electron density is spread unevenly over the whole of the atom, rather then be fixed on one position

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5
Q

double bond

A

a chemical bond between the chemical elecments involving 4 bonding electrons insteed of 2

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6
Q

boiling point

A

temp when vapour pressure equals external pressure

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7
Q

CRITIAL temp

A

the temp about which the gas cannot be made to liquify, no matter the pressure applied

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8
Q

critical pressure

A

the min require to be applied to bring about liqefraction at critical temp

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9
Q

emulsion

A

a mix in which the liquid contains are immiscible in nature hence causing emulsion

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10
Q

suspension

A

a mix in which a solute particle do not dissolve but get suspended throughout the bulk of the solvent

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11
Q

coagulation

A

physical reaction, the action of a liquid to change to a solid or a semi-solid state.

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12
Q

micelle

A

it is aggregate of surfacent molecules dispured in liquid colloid

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13
Q

solubility

A

the ability for a given substance to solute ( to dissolve in solvent)

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14
Q

oxidation

A

loss of e

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15
Q

reduction

A

gain of e

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16
Q

galvanic cell

A

a electrochemical cell that uses transfer of electrons in redox reactions to supply electric current

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17
Q

electromotive force

A

a difference in potential that tends to give an electical current

18
Q

colligative properties

A

depends upon conc of solute molecules

19
Q

electrolysis

A

unit of electic current being converted into chemical energy

20
Q

Ionization energy

A

energy required to remove the most loosely held electron from one mole of gaseous atoms to produce one mole of gaseous ions each with a charge of 1+

21
Q

Electron affinity

A

The amount to energy released when an electron is added to a neutral atom or molecule in the gaseous state to form a negative ion

22
Q

First law of thermodynamics

A

In any change that occurs in nature, the total energy of the universe remains constant (a version of the law of conservation of energy). The energy may be converted from one form to another.

23
Q

Second law of thermodynamics

A

The entropy of an isolated system never decreases, because isolated systems always decay toward thermodynamic equilibrium, a state with maximum entropy.

24
Q

Third law of thermodynamics

A

The entropy of a perfect crystal, at absolute zero Kelvin, is exactly equal to zero.

25
Q

Hess’s law

A

(of constant heat summation)
The enthalpy change of a reaction is the same, regardless if the pathway (whether it is completed in one step, or in several steps)

26
Q

hunds rule

A

two or more orbitals of equal energy are available, electrons will occupy them singly before filling them in pairs

27
Q

Aufbau principle

A

It states that as the electrons are added, they assume their most stable conditions (they fill the orbitals starting at the lowest possible energy levels (e.g. 1s before 2s).

28
Q

Pauli Exclusion Principle

A

It is impossible for two electrons of a poly-electron atom to have the same values for the four quantum numbers

29
Q

Henry’s law

A

The solubility of a gas in a liquid is directly proportional to the partial pressure of the gas above the liquid

30
Q

Avogadro’s law

A

Equal volumes of all gases, at the same temperature and pressure, have the same number of molecules

31
Q

The Lewis acids

A

Lewis acid: free electron pair acceptor

32
Q

Lewis base

A

: free electron pair donor

33
Q

proprotion

A

A pure compound always contains different elements, combines in the same proportions by mass

34
Q

multiple proportions

A

If two or more compounds are composed of the same two elements, the ratio of the masses of one element that combine with a fixed mass of the other element is a simple whole number

35
Q

Multidentate ligand

A

Ligands with more than one donor atom are capable of occupying more than one position of a metal ion to form cyclic complexes called chelates

36
Q

coordination number

A

Number of ligands around the central ion in the coordination sphere

37
Q

Boyle’s Law

A

At constant temperature, the volume of a fixed mass of gas is inversely proportional to its pressure.

38
Q

Charles’ Law

A

At constant pressure, temperature is directly proportional to volume ( gases expand when heated)

39
Q

Gay-Lussac’s Law

A

At a constant volume, the pressure of an ideal gas is directly proportional to its temperature.

40
Q

Arrhenius concept

A

Acid: produces H+ ions in water
Base: produces OH- ions in water

41
Q

Brønsted-Lowry base

A

accept a proton from another molecule

42
Q

Brønsted-Lowry acid

A

donated a proton to another molecules