Deck 4 Flashcards

1
Q

A covalent bond is?

A

A covalent bond is a bond formed by a shared pair.

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2
Q

Explain the forces involved and overcome in a covalent bond.

A
  • The negatively charged electrons are attracted to the positive charges of both nuclei.
  • This attraction overcomes the repulsion between the two positively charged nuclei.
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3
Q

Is a covalent bond directional ?

A

Yes

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4
Q

Draw the dot and cross diagram for H2O

A
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5
Q

Draw the dot and cross diagram for the covalent bonding of NH3.

A
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6
Q

What is a lone pair?

A

A lone pair is an outer-shell pair of electrons that is not involved in chemical bonding.

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7
Q

Note:

A

Lone pair are concentrated regions of negative charge.

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8
Q

Draw the dot and cross diagram for CO2

A
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9
Q

What is a dative covalent or coordinate bond?

A

A dative covalent or coordinate bond is a shared pair of electrons which has been provided by one of the bondinbg atoms only.

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10
Q

Draw how a dative covalent bond can be indicated in a diagram.

A

Instead of A-B, it would be A->B

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11
Q

Draw the dot and cross diagram for an ammonium ion.

A
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12
Q

Draw the ammonium in using the elemeny symbols.

A
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13
Q

Note:

A
  • Once formed, a dative covalent bond is equivalent to all the other covalent bonds.
  • For example, in the NH4*ion, you cannot tell which bond was formed from the N lone pair.
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14
Q

How many covalent and dative bonds does an ammonium ion have?

A

1) Three covalent bonds
2) One dative covalent bond.

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15
Q

What is the oxonium ion?

A

When an acid is added to water, water molecules form oxonium ions, H3O*. For example, hydrogen chloride gas froms hydrochloric acid when added to water:

HCl(g)+H2O(l)—->H3O*(aq)+CL-(aq)

H3O* ions are responsible for reactions of acids. In equations, the oxonium ion is often simplified as H*(aq).

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16
Q

Why might the outer electrons surrounding an atom in covalent bonding may not follow the octet rule?

A
  • There may not be enough electrons to reach an octet.
  • More than four electrons may pair up in bonding.(expansion of the octet.)
17
Q
A