Deck Flashcards

1
Q

Grignard

A

No OH

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2
Q

Grignard with primary alkyl halide

A

Makes new c-c bond

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3
Q

Strong base grignard

A
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4
Q

Only reduce once, just right, O to H:-
(Stops at alkyl halide)

A

Baby bear, DIBAL-H

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5
Q

Gentler less reactive reducing agent O to H:

A

Caregiver bear NaBH4 MeOH

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6
Q

Reducing evertyhing possible replace bonds O woth H:-

A

Monster LiAlH4

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7
Q

Reaction at alpha carbon halogenation acid and base

A
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8
Q

Grignard react with esters or acid chlorides

A
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9
Q

1,2 and 1,4 addition

A
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10
Q

Grignard react with carbonyl carbons

A
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11
Q

Kinetic vs thermodynamic

A
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12
Q

Crossed aldol

A
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13
Q

Mixed and direct aldol

A
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14
Q

Transesterification with acid or base

A
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15
Q

Strong base with alpha carbon

A
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16
Q

Heal the cleaver with

A
17
Q

Tone down to react with c.a. Kt ester not ketone

A
18
Q

Self condensation aldol with mild base or acid

A
19
Q

Controllable Beta-ketoester

A
20
Q

How to make a ring

A
21
Q

React with bears

A
22
Q

Michael addition enolate and aldol

A
23
Q

Claisen

A
24
Q

Tautomerization

A
25
Q

Imines

A
26
Q

Use amines to make amides primary and secondary

A
27
Q

Reduce imine to secondary amine

A

Cat lady bear