Day 1 - SLU COMPI Flashcards
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Which of the following would you expect to form the strongest bonds to carbon? A. Li B. Na C. K D. Rb
A
Consider the following reaction at 1600˚C: Br2(g) ↔ 2Br(g).
When 1.05 moles of Br2 are placed in a 2L flask, 2.5% of Br2undergoes dissociation. Calculate the Kp for the reaction. A. 0.20869 B. 0.001346 C. 3.7216 D. 0.0953
B
What will be the likely combination of ionization energy and electron affinity for an element that has a very low electronegativity? A. High ionization energy, high electron affinity B. High ionization energy, low electron affinity C. Low ionization energy, high electron affinity D. Low ionization energy, low electron affinity
D
Consider the reaction: PCl5(g) ↔ PCl3(g)+ Cl2(g)
ΔHrxn = 87.9 kJ/mol
Which of the following will result in the increase in concentration of Cl2 gas? a. Add PCl 3 B. Cool the mixture C. add PCl 5 D. increase the pressure
C
The average atomic mass of Ga is 69.72. Naturally occurring Ga is composed of 60.0% 69Ga, which has an atomix mass of 68.91, and 40.0% 71Ga. What is the atomic mass of 71Ga? a. 69.72 amu b. 69.92 amu c. 70.94 amu d. 71.00 amu
C
All of the following are chemical processes except
a. Liquid vaporizing to form a gas b. The conversion of starch to carbon dioxide and water in an animal c. An acid dissolving a metal d. Rusting of iron
A
In what group of the periodic table is the element with the following electron configuration? [Ar] 4s2 3d10 4p3 a. 1A b. 2A c. 3A d. 5A
D
The vapor pressure of water at 25˚C is 23.756 torr. A solution consisting of 18.913 grams of a non-volatile substance in 36 grams of water has a vapor pressure of 20.234 torr. What is the molecular weight of the solute? a. 62 b. 54 c. 48 d. 39
B
The atomic weight of chlorine is 35.45 and its naturally occurring isotopes are Cl-35 and Cl-37. What is the percentage abundance of Cl-35? a. 95.8% b. 98.7% c. 77.5% d. 75.0%
C
Starting with 1.0 gram of Sr-90, 0.953 grams will remain after 2 years. Calculate the initial activity of Sr-90 in Ci. 1 Curie(Ci)= 3.70 x 10^10 disintegration/sec a. 70 b. 140 c. 210 d. 280
B
Starting with 2-methyl-2-butene, which of the following processes must be used to produce a secondary alcohol? a. Acid-catalyzed hydration b. Oxymercuration-demercuration c. Addition of bromine water d. Hydroboration-oxidation
D
The Lewis structure of SF2 has ___ lone pairs of electrons and ___ double bonds. a. 8,0 b. 6,0 c. 4,1 d. 2,2
A
When a straight chain alkene undergoes sulfuric acid catalyzed hydration, the primary product is a a. primary alcohol b. secondary alcohol c. tertiary alcohol d. quaternary alcohol
B
How many isomers are there of the chlorinated alkane with the formula C3H6Cl2? a. 2 b. 3 c. 4 d. 5
C
Lead (Pb) crystallizes in a face-centered cubic lattice with a unit cell edge of 4.941. What is the density of lead? (l = 10^-8 cm) a. 2.78 x 10-14 g/cm3 b. 2.85 g/cm3 c. 5.70 g/cm3 d. 11.4 g/cm3
D
The energy sublevel that can contain the most electrons is specified by which of the following quantum number descriptions? a. n=2, l=1 b. n=3, l=2 c. n=4, l=3 d. n=5, l=0
C
To answer the following question, you will need to recall for the 14C isotope found in living matter t = 5720 years and the decay rate is 15 decays/g.min. If 20 grams of charcoal scrapings from the wall of a prehistoric cave dwelling are decaying at a rate of 2.0 disintegrations/minute then the writings must be a. 500 yrs old b. 5720 yrs old c. 11000 yrs old d. 22000 yrs old
D
How many monochlorinated product is expected from the chlorination of propane? a. 1 b. 2 c. 3 d. 4
B
A compound containing only C and H gives 0.518 g of H2O and 2.13 g of CO2 when fully combusted in oxygen. What is its simplest or empirical formula? a. CH9 b. C5H3 c. C5H6 d. C3H4
C
Hydrolysis of an ester leads to two compounds. Which of the following pairs compounds is formed from such a hydrolysis? a. an alcohol and an aldehyde b. two alcohols
c. an alcohol and a carboxylic acid
d. a ketone and a carboxylic acid
C
What is the molarity of a KMnO4 solution standardized against 1.356 gram Na2C2O4 requiring 25.1 mL of the solution in acidic medium?
a. 0.161 M b. 0.403 M c. 1.008 M d. 0.856 M
A
The 300 mg sample of impure Na2SO4 (MW= 142.04) was dissolved in sufficient water and the sulfate was precipitated by the addition of 35.00 mL of 0.1022 M BaCl2. The precipitate was removed by filtration and the remaining BaCl2 consumed 6.79 mL of 0.2467 M EDTA for titration to the Calgamite endpoint. Calculate the purity of the sample.
A. 80% B. 85% C. 90% D. 95%
C
25 mL of a monoprotic unknown acid is titrated to an end point with 0.10 M NaOH at 32.2 mL. At the point where 16.1 mL of base has been added, the pH of the solution is 5.5. What is the value of Ka for the unknown acid?
A. 1.6x10-6 B. 3.2x10-6 C. 6.4x10-6 D. 1.3x10-5
B