Dating and random bits Flashcards

1
Q

When was cast iron invented

A

5th century in china

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2
Q

What is a Catalan forge

A

Cold air blast.

Falling water is used to act as a compressor.

Higher temperatures achieved, but still uses charcoal, and produces pig iron.

This is undesirable because higher temperature (upto 1200oC) mean that liquid iron is created and causes Carbon pick-up.

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3
Q

What is Pig iron

A

where lines run off the base of the forge in lines (like pigs drinking milk from stomach)

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4
Q

When was the iron bridge built? How was it constructed?

A

(1781), constructed with wood joints, built as if it was being built with wood. Not welded together. All pieces cast individually. Bridged into gorge.

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5
Q

What is the metastable phase on the Fe Fe carbide phase diagram

A

Fe3C marsenite

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6
Q

What is bloomers iron?

A

ferrite+ pearlite. Forms flake and SG (spheroidal graphite iron)

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7
Q

Give some properties of graphite

A

Graphite is very brittle, shouldn’t be used to build anything. It is very low strength and brittle.

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8
Q

What is Flake grey cast iron?

A

graphite flakes with pearlite. Formed due to alpha + graphite, eutectic transformation. If a tensile load is applied, matrix supports all of the applied load.

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9
Q

What is Spheroidal grey

A

some C content, microstructure altered to get graphite, spheres improve mechanical properties, greater distance between graphite sphere is best shape for avoiding STRESS RAISERS. Graphite wraps itself around itself and structure is built up from cone like structure/ segments.

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10
Q

Why is the Fe-Fe carbide diagram not an equilibrium diagram?

A

because Fe3C is not an equilibrium compound –> breaks down even with no driving force.

Can get a equilibrium diagram – has a eutectic point where austenite (alpha) + graphite formation occurs.

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11
Q

What happened in 2500BC

A

Chinese made SG

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12
Q

What happened in 1600 BC

A

western were making flake grey iron

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13
Q

What is compacted graphite iron

A

intermediate form between flake and spheroidal, properties are halfway between.

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14
Q

1943

A

added mg to cast iron – solidified, formed spheres ductile iron

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15
Q

1948

A

successful production of spheroidal graphite in hypereutectic grey iron by addition of small amounts cerium

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16
Q

1808

A

– discovery that al could be produced by electrolytic reduction from alumina

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17
Q

1825

A

Hans Oersted (Denmark) was successful

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18
Q

1920’s

A

addition of salt to Al-Si alloy  modification, sodium had effect on silicon structure, forms Al dendrites with eutectic structure alpha + Si. When NaCl added into melt long shape changed to a finer structure, gives double the mechanical properties associated with silica.

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19
Q

What is faceting?

A
    • graphite facite – ledge builds up into angular structure –> silicon needles & blocks.
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20
Q

Why did the Chinese have SG before the west?

A

1) Normally Al-Si alloys produce facetted eutectic Si
2) Al-Si with Na modifies & (Si) prevents growth along edges – addition of Na + Si increases properties
3) Chinese iron ores were high purity – when Fe produced contained eutectic (facetted) graphite spheres
4) In the west – iron ores contaminated with S&P – pig iron acted as modifiers leading to reduced properties

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21
Q

What is the composition of steel?

A

upto 12%C – grains of ferrite & pearlite.

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22
Q

What is peralite

A

lamellae of ferrite & cementite.

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23
Q

Describe carburisation/ nitidisation

A

diffusion of carbon from exterior to interior of microstructure. Heating in C rich atmosphere: C diffusion into surface, because surface cooled more quickly than interior. Quenching  surface martensitic layer (brittle) & tougher inner pearlite core.

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24
Q

Boiling curve?
Nucleate boiling?
Transition boiling?

A

rapid cooling at the surface creates a temperature gradient.

Nucleate boiling: formation of nuclear bubbles, bubbles penetrate surface flaws, pocket of water vapour, bubbles then released.

Transition boiling: vapour film forms and collapses continuously.

25
What is pattern welding
patterns are a by product of process. Sword made from thin sheets of carburised iron – thin sheet allows a homogeneous C-content to be achieved. “Piling” / welding sheets  sword with varying properties E.g. Nydan sword 3rd century AD. Surface carburised strips could be forged together  make a layered structure with a more homogeneous C content (up to ~ 0.5%)
26
Describe the 4 properties of pattern welding
1) Medium -C core (0.5% C) 2) Backed either side with soft iron strip 0.1% C 3) Either side are 6 piled & twisted strips (0.1-0.5% C) 4) Cutting edge made from plain C-steel
27
Damescening?
pattern welding with finer steel strips & more of them. Suggested that it takes 25 hours to make, 128 reheats to weld pieces together
28
Wootz steel?
damascening using layers of higher C steel (contains cementite), or fragments of cast iron mixed with low-C bloom steels
29
Describe steel making cementation
Bars of wrought iron are packed together in furnace (c.1100) for ~ 1 week. Carbon diffused into steel  0.1% C (blister steel). Bars, cut, forged and reheated to create a more homogeneous composition (shear steel).
30
What is Hunstman's crucible steel made from?
1) Carburised wrought iron, solid: low C, carburisation | 2) Decarburised cast iron, decarburisation of High C cast iron
31
Describe the Hunstman process
Hunstman (1740) developed process where coke used as fuel (de-volatilised coal), to obtain high furnace temp. Blister steel (~0.1%C) was melted in pots with a flux, and cast to shape. As a liquid is involved, carbon pick-up from coke occurred, increasing C content of the steel
32
Bessemer converter?
method for reducing C-content of liquid cast iron by blowing in air. Oxygen reacts with C in iron  CO2, lowers C-content, subsequent deoxidisation process is required to remove residual oxygen dissolved in the melt (otherwise embittle the steel)
33
describe the modern steelmaking ironmaking process
Iron as Fe2O3 & Fe3O4 reduced by reaction with C, from coke; Fe203+3CO --> 2Fe +3CO2 In blast furnace at high temperature, high carbon content liquid iron. Steel has low C content (0-1.4wt %) reduce C content a lace is used to blow oxygen trough liquid steel: O2 +2C = 2CO. Liquid steel contains too much O, reduced by added element with strong preference for reaction with O: Si + O2 = SiO2 2Al + 3O2 = 2Al2O3 Deoxidisation products should float out from steel – removed with the slag, mat become trapped as inclusions. Final stages i) Degassing to remove N under vacuum ii) Removal of impurities S,P by reaction with slag iii) Alteration of composition by addition of ferroalloys Mn, Cr, Ni… iv) Stirring with Ar gas to make T & composition uniform
34
Name and describe the 3 types of malleable iron
White cast iron with pearlite matrix. Subsequent annealing causes (metastable) cementite to decompose to graphite. 3 forms : • Whiteheart malleable – heating casting to 900°C in an oxidising atmosphere results in surface decarburisation. • Blackheart malleable – heating casting to 900°C in a neutral atmosphere results in decomposition of iron carbide into a graphite rosette shape, (which does not have the disadvantages of graphite flakes in cast iron). • Pearlitic malleable – heating to 900°C and then rapid quenching produces a pearlitic or martensitic matrix.
35
What is the diffusion model
implicit model of the human past based upon diffusion items dated by association
36
Give an example of a useful date list
king-list of Persia to astronomical events, (e.g., the helical rising of Sirius), however, this only extends back to about 800 BC
37
how were the neolithic tombs dated
initially thought to be built by Mycenaeans - corralled roofs dated the Egyptian chronology 1500BC so must be later (giving time to sail) so around 1200BC
38
What is seriation
relative dating method , if object found at same archeological level as another assumed to be form the same period, older objects found below
39
describe c-14 dating
absolute dating method developed in late 1940's by willard libby living organisms take up C, C-14 has half life of 5730 yrs c14 in atmosphere produced by cosmic ray neutrons interacting with n14. at point of plant death organism has same amount of c14 as in atmosphere dating by measuring amount of c14 present now and relating to amount of stable 12C by emissions of beta, or mass spectroscopy
40
why does C14 dating need calibration
because 14C content in the atmosphere is not constant past c14 data achieved from long lived trees that could be dated by counting growth rings
41
What does accurate radiocarbon dating require
(i) . The calibration curve is not smooth, but has plateaus in it. This means applying the calibration curve results in a range of equally possible dates. (iii) . Different types of samples give different results. (iv) . Fractionation. Where different C isotopes, having different atomic masses, are processed in different ways. (v) . Reservoir effects. For example, molluscs extract carbonate dissolved in sea water, which is depleted of 14C; molluscs were a valuable contribution to the diet and are thus often radiocarbon dated, but this would make them appear older than they actually are
42
Sr- isotope analysis?
uses the 86Sr / 87Sr ratio nature of the geology influences the diet, which is expressed by measurement of the Sr isotopes in the tooth enamel of skeletons. Knowing the Sr isotope ratio one can assign a possible origin for an individual
43
Dendrochronology
trees grow I bark ring per year, can be thick or thin depending on the climate sereis has been put together dating back to 26,000 yrs ago gives precise date for wood, if the bark is still attached
44
Describe the hardness test
Indentor is forced into the surface of a material, until it reaches an equilibrium depth. The diameter of the impression is then measured, and related to an arbitrary hardness scale
45
Describe the Brinell test
uses a steel ball indentor, the Rockwell and Vickers test use conical and pyramid-shaped indentors, respectively. The Knoop tests uses an elongated pyramid for determination of micro-hardness
46
what happens as the inventor in a harness test is forced into the material
material must plastically deform, and flow away from the moving indentor. The hardness test measures: ability of a material to elastically and plastically deform, relationships between the measured hardness of a material, and its tensile properties.
47
when do materials creep
Materials will creep (i.e., deform) under a low load, particularly at elevated temperatures. In creep terms, elevated temperatures means at T > 0.4 Tm
48
what is the most famous example of creep
turbine blades in jet engines. These are operated at temperatures close to their melting point, and under great stress due to the high density of the material, (a Ni-based alloy), and the centrifugal forces that consequently occur during operation
49
how is creep resistance achieved
improved by directional solidification; this aligns columnar crystals in the direction of loading, which means that the grain boundaries are aligned parallel to the centrifugal force the blades experience
50
What happens during a creep test?
standard specimen is held in a furnace at the temperature of interest, (with an inert atmosphere if necessary) and its deformation recorded as in a tensile test. This gives rise to the characteristic creep curve, which shows regions of primary creep, secondary creep, and tertiary creep, leading to failure creep accelerated as usually takes place over a number of years
51
why does fatigue occur
due to cyclic loading with a stress below the normal failure stress of the material
52
how are fatigue tests carried out?
at defined stress amplitudes, where the stress varies from a maximum to a minimum, giving a characteristic stress amplitude; S = stress.a = (stress.max - stress.min)/2 The number of cycles to failure is recorded, which can be typically in the range of 105 to 106, and plotted on an S-N curve.
53
How do fatigue failure originate
originate from a flaw, often a surface flaw concentration of the applied stress occurs at the tip of such a flaw; crack can initiate from this point and slowly grow across the section with each application of the cyclic load. Once CSA< an area below that which can support the applied load, the crack propagates rapidly across the section, leading to sudden failure
54
how is the fracture surface characterised
by concentric rings
55
Statergies to reduce or prevent fatigue failure
(i) . improving the surface finish to reduce surface flaws that might act as crack initiators. (ii) . Eliminating internal defects, such as pores or inclusions, that could also act as crack initiators. (iii) .design modifications to reduce stress raisers (iv) . surface treatments (in metals) such as shot-peening or carburising, which will impart compressive residual stresses to the surface and reduce surface-related crack initiation.
56
describe impact testing
A standard specimen is placed in a fixture, and a weighted arm released to swing down and impact on the specimen. The specimen is notched to ensure its fracture, and the height to which the arm reaches, after passing the specimen, is used as a measure of the energy absorbed by fracturing the specimen
57
what phenomenon to steels exhibit
ductile-brittle transition caries with steel composition, generally around -30oC to -50oC
58
when does the brittle failure of steels usually occur and what is the implication?
use at low temperatures sinking of the liberty ships in WW2 because of the welded construction, and in the sinking of the titanic