D15: Finishing and Packaging Flashcards
What is post-fermentation clarification?
- all processes, physical and chemical, that are used to make wine clear
- processes used to clarify grape must - particularly sedimentation, centrifugation - also used to clarify wine
- wine may also be fined and filtered
Describe the process of sedimentation
1) if stored in cool cellar, wine will begin process of clarification naturally
2) suspended matter precipitates over time
3) wine is allowed to stand, particles with higher density than wine will form a sediment at the bottom of the container
4) wine is then racked off, leaving sediment behind
5) number of rackings depends on size of container and labour availability
6) larger the vessel, greater number of rackings required to avoid thick layer of sediment
7) can get prem wines clarified this way so that they don’t lose flavour, aroma or texture through fining or filtering
8) takes time so wine can’t be released until ready so only suitable for prem/super-prem wines
9) if barrel ageing, sedimentation happens as part of barrel ageing process
Describe centrifugation
1) accelarating process of clarification
2) used in high volume processes and wineries
3) spins wine at high rotational speed to clarify it
4) can replace depth filtration
5) allows for early bottling
6) effective if wines have lot of matter in suspension
Describe Fining
1) fining agent added to speed up process of precipitation of suspended material in wine
2) can be of protein or mineral origin
3) removes small proportion of unstable COLLOIDS (microscopic particles too small to be removed by filtering) from wine
4) clarifies wine and stabilises against formation of hazes later in bottle
5) need to conduct lab tests before using to ensure that minimum effective amount is used
6) then compare fined sample with original wine before proceeding to ensure fining agent has removed positive compounds from the wine or are making it unstable if too much is added (OVER-FINING)
7) each fining agent has particular properties that can offer solutions to problems e.g. removing tannins or browning white wines
8) need to ensure fining agent has OPPOSITE CHARGE from wine colloid to be removed
9) fining agent and colloid attract each other and form a solid which is large enough to be removed by racking or filtration
What are the three categories of common fining agents?
1) those that remove unstable proteins
2) those that remove phenolics that contribute undesirable colour and bitterness
3) those that remove colour and off odours
What agent is used in fining to remove unstable proteins?
BENTONITE
- form of clay which absorbs unstable proteins and unstable colloidal colouring matter
- has minimal effect on flavour and texture of wine
- does lead to some colour loss in red wines
- produces large amount of sediment so wine is lost when wine is racked off
Why do you need to remove unstable proteins from wine (during fining?)
- need to remove grape-derived proteins
- this is only relevant to white wines and rose wines
- proteins can agglomerate into visible haze if warmed (e.g. in transit)
- would be seen as a fault so wines need to be fined with BENTONITE
What SIX fining agents are used to remove phenolics that contribute undesirable colour and bitterness?
- Egg white
- gelatin
- casein
- isinglass
- vegetable protein products
- PVPP
Describe the role of egg whites in fining
removing phenolics that contribute undesirable colour and bitterness
- good protein content
- used in powder or fresh form
- used for high quality red wine as good as removing harsh tannins and good for clarifying wines
- gentle to wine
- must be declared on label as it is an allergen (for EU and other territories)
Describe the role of gelatin in fining
removing phenolics that contribute undesirable colour and bitterness
- protein collagen extracted from pork
- aids clarification
- removes bitterness and astringency in red white pressings
- prevents browning in white wine pressings
- added in very small amounts as very easy to over-fine with gelatin, strips out flavour and character, creates risk of protein haze forming later
- not suitable for vegetarian wine as it is derived from animals
Describe the role of casein in fining
removing phenolics that contribute undesirable colour and bitterness
- milk-derived protein
- removes browning from white wine
- clarifies wine
- needs to be declared as allergen in some places
Describe the role of isinglass in fining
removing phenolics that contribute undesirable colour and bitterness
- protein collagen
- effective clarifyer for white wines, brightening their appearance
- smallest effective amount must be added to avoid potential for formation of protein haze later and creation of a fishy smell
- not suitable for vegetarians as derived from fish bladders
Describe the role of vegetable protein products in fining
removing phenolics that contribute undesirable colour and bitterness
- derived from potato or legumes
- suitable for vegan friendly wines
Describe the role of PVPP in fining
removing phenolics that contribute undesirable colour and bitterness
- polyvinylpolypyrrolidone
- insoluble plastic in powder form that removes browning and astringency from oxidised white wine
- gentler fining agent that charcoal
- rarely used on red wines
- can reduce astringency and brighten the colour
What role does Charcoal play in the fining process?
Removing colour and off-odours
removes brown colours (e.g. to create Pale Cream Sherry) and some off-odours
- can easily over-fine and remove desirable aromas and flavours
- option of treating only one batch of wine and blend it with rest of wine to reduce effect
What is Filtration?
- physical separation technique used to eliminate solids from a suspension by passing it through a filter
- filter has porous layers that trap solid particles, making the liquid clear
- most common way of clarifying wine
- some critics and winemakers believe fining affects wine’s character, stripping it of texture - hence why some bottles are bottled unfiltered
- two compensation theories: 1) wine recovers from shock of filtration in a few months 2) less chance of wine developing faults later during ageing
Describe Depth filtration
- traps particles in depth of material that forms the filter
- can cope with fluid with many particles in it (e.g. wine that has just been pressed or contains lees)
- small particles are trapped within irregular channels in the filter
- doesn’t block easily
- can be unreliable as some particles can make it through the filter if pressure is too hard, or if the filter is used too long
- not an absolute filter
What is Diatomaceous Earth?
Depth filtration
- AKA kieselguhr
- most common form of depth filtration
- once processed, it is pure silica and inert
- comes in range of sizes so can remove very large or very small particles
- needs to be disposed of responsibly which add additional cost
What is a rotary vacuum filter?
- use this to filter very thick and cloudy wine (e.g. wine mixed with lees)
- oxidative process as drum is exposed to air
What is an enclosed DE filter?
Part of the Diatomaceous Earth family
Does the same job as a rotary vacuum filter
Can be flushed with inert gas to avoid oxidation
What is a sheet filter?
- known as ‘plate and frame’ or ‘pad’ filters
- wine passed through sheet of filtering material
- more sheets in the filter, quicker the wine can be filtered as any portion of wine only passes through one sheet
- very fine graded sheets can be used to remove any remaining yeast as bottling
CONS:
- require initial upfront investment but cost of sheets are low
- need trained personnel to operate them properly
What is surface filtration?
- stops particles that are bigger than the pore size of the filter from going through
- can be known as ‘absolute filters’
What are the two types of surface filters?
- membrane filters
- cross-flow filters
What is a membrane filter?
- commonly used during bottling/packaging process
- can be called CARTRIDGE FILTERS
- catch particles that will not go through pore size of filter
- slower than depth filter as pores are smaller
- wine must be pre-fitered first (e.g. by depth filter) or else membrane filters get easily blocked
What is a cross-flow filter?
- also known as TANGENTIAL FILTERS
- allow wine to pass through filter while cleaning surface of filter while it works
- solids cannot pass through filter
- can filter wine with high load of particles or lees very quickly
- no replacement sheets/cartridges to buy/dispose of
- machines are expensive so better for large or well-funded wineries
Describe stablisation
- stablisation used to refer to winemaking interventions which, if not done, could lead to undesired effects in final wine
- unwanted hazes, deposits in bottle, rapid changes in wine (browning)
- tartrate stability, fining, filtering - all contribute to clarification and stabilisation
What do you use to achieve protein stability?
BENTONITE
Tartrate stability
where harmless deposits of crystals that form in finished wine
- POTASSIUM BITARTRATE or CALCIUM TARTRATE
- customers could regard these as faults so most winemakers will look to prevent this from happening
What are the six process which can be used for tartrate stability?
Cold Stablisation
Contact Process
Electrodialysis
Ion Exchange
CMC (Carboxymethylcellulose)
Metatartaric Acid
Describe cold stablisation
tartrate stabilisation
- can be dealt with by wine being kept in a cold cellar for months during winter
- wine needs to be held at -4 degrees for about 8 days so crystals form before bottling and these can then be filtered out
- requires equipment and cost of energy to refrigerate wine
- COLLOIDS must be removed by fining before this process as they can prevent crystals forming at this stage
- this process only removes POTASSIUM BITARTRATE and not calcium tartrate
Describe Contact Process
tartrate stabilisation
- quicker, continuous, more reliable, cheaper
- POTASSIUM BITARTRATE is added to the wine and speeds up start of crystallisation
- wine is cooled to 0 degrees
- after a couple of hours, crystals are filtered out
Describe Electrodialysis
tartrate stabilisation
- charged membrane is used to remove selected ions
- high initial investment but total costs are lower than cold stablisation and process uses less energy and is quicker
- removes potassium and calcium ions and tartrate ions
- allowed in EU and some other territories
Describe Ion Exchange
tartrate stabilisation
- doesn’t remove tartrates
- replaces potassium and calcium ions with hydrogen or sodium ions which will not drop out of solution
- not allowed in some territories as replaces potassium with sodium (not good for health)
- although, resulting levels in wine are well below limit
Describe CMC
tartrate stabilisation
- cellulose is extracted from wood and prevents tartrates from developing to a visible size
- widely used on inexpensive white and rose wines
- not suitable for reds as reacts with tannins and causes haze
- much cheaper than chilling
- keeps wine stable for few years
Describe Metatartaric Acid
tartrate stabilisation
- prevents growth of potassium bitartrate and calcium tartrate crystals
- reduces need for cold stabilisation
- compound is unstable
- positive effect is lost over time - especially if wine is stored at high temps (25-30 degrees)
- quick and easy process that is used more for red wine (mainly as CMC is better for whites)
What is microbiological stability?
- wines with residual sugar are potentially liable to start re-fermenting in the bottle
- can be dealt with by removing yeast through sterile filtration
- alternative, can add SORBIC ACID and SO2, which inhibits yeast from growing
- negative: some people can smell SORBIC ACID
- very few microbes can live in wine with low pH and high alc levels
- exceptions: LACTIC ACID BACTERIA and BRETT
Microbiological Stability: Lactic Acid Bacteria
- wines with lactic acid bacteria which haven’t gone through MLC are liable to MLC starting in bottle (causing cloudiness)
- need to ensure LMC has been completed or wine is filtered to remove bacteria
Microbiological Stability: Brettanomyces
- wine can be treated with DMDC (dimethyldicarbonate)/Velcorin before bottling
- inactives Brettanomyces
What options must a winemaker consider when finishing his wine?
- before options can be considered, winemaker must do FULL CHEMICAL ANALYSIS
- measuring:
- alcohol
- residual sugar
- free SO2
Can then decide to:
- adjust SO2 levels
- reduce dissolved O2
- add CO2