D1 - Winemaking Flashcards
Sources of aroma compounds of wines
- from grapes - methoxypyrazines and rotundone
- from grape precursors - Thiols and terpenes
- fermentation by products - esters, acetaldehyde, diacetyl, sulphur compounds
- oak - vanillin, lactones
What does alcohol contribute to wine?
- fullness of body and mouthfeel
- sense of sweetness
- oral warmth
- above 14.5% it reduces aroma volatility and increases bitterness
Key characteristics of tannins
- they bind with proteins in the mouth, producing a dry sensation
- when unripe they impart bitter taste
- RS can make them feel softer
- high acidity makes them feel harder
EU classification for sweetness levels in still wines
- dry / sec / trocken - <4g/L
- medium dry / demi-sec / halb-trocken - 4 - 12g/L
- medium sweet / moelleux / lieblich - 12 - 45 g/L
- sweet /doux / suss - > 45g/L
What is the foundation the conventional modern viticulture?
scientific understanding of the processes which convert must into wine.
The starting point was Luis Pasteur’s identification of yeast and bacteria in 1860
Tools used by conventional winemaking
- Temperature control
- use of additives and processing aids
- manipulations with different levels of technology and complications
Who can issue organic winemaking certifications?
- associations
- country authorities
- the EU
What does “organic winemaking refer to?
Production of wine from organically-certified grapes, and complying with rules that restrict some practices.
Levels of organic winemaking in the USA
- Organic Wine - no added SO2
- wine made from organic grapes
Are Biodynamic winemaking practices universal?
No, they vary across countries.
Dementer sets guidelines, but each country’s body set their own specifications.
What is the natural winemaking tenet?
“nothing is added, nothing removed”
What are the winemaking decision that are generally agreed as essential for natural winemaking?
- ambient yeast
- no filtering or fining
- no, or minimal, addition of SO2
- use of organic/biodynamic grapes
Effect of Oxygen in wine colour
- red wines lose colour and turn tawny
- white wines become darker and turn golden, an then brown
Ways of reducing Oxygen exposure
- Avoiding Ullage
- Use of inert gases
- Addition of SO2
- use of impermeable containers
- keep cool constant temperatures
- seal the bottles with screw cap or vinolok
How can Oxygen exposure be increased?
- Avoiding ullage without the use of inert gas
- use of cap management techniques that spray the wine
- use of small wooden barrels
- increase the number of rackings and lees stirring
- micro-oxygenation
- hyper-oxidation
Positive role of Oxygen
- hyper-oxidation removes fragile components achieving longer shelf life
- gives the fermentation a quick start
- revitalises yeast if fermentation slows down
- prevents reductive taint during bottle-ageing
- triggers development of flavour compounds that provide “character”
- Improves colour stability
- promotes tannin polymerisation - softening
Properties of SO2
- Antioxidant
- Antimicrobial/Antiseptic
- Anti-oxidasic
Forms in which SO2 can be added to the must/wine
- gas
- liquid
- solid - sulfur dioxide, potassium metabisulfite or potassium bisulfite
Critical winemaking stages at which SO2 is normally added
- freshly harvested grapes
- after crushing/ before clarification in whites
- after AF in whites or MLF in reds
- prior to bottling
Key points of chilling the grapes at the reception in the winery
- crates with the grapes are placed in a store room for hours
- grapes in a semiliquid state can be chilled by a heat exchanger
- it reduces the rate of oxidation
- particularly valuable in regions with high summer temperatures
- increases cost and slows down the processing of the grapes
- can be advantageous when processing several different grapes/plots
When can the sorting of the grapes be carried out?
- at the vineyard
- at the reception
- after destemming
ways of sorting the grapes at the winery
- by hand in a table of conveyor belt
- by a high-tech machine that scans individual grapes
how can the grapes be moved when they are received at the winery?
- with a conveyor belt
- screw conveyor (lower potential quality)
- manually with a forklift
What does the term crushing refer to?
to the application of pressure to break the skin of the grape and release the juice, so that it is available for fermentation
What is the aim when pressing must for white wine production?
Maximising the juice extraction without extracting tannins and avoid an excessive amount of solids
What is the aim when pressing red wines?
Maximising the amount of wine extracted without breaking the seeds, which are soft after the maceration and would otherwise impart an overtly bitter taste
Name the different types of presses
- Pneumatic
- basket
- horizontal screw
- continuous
Explain the mechanism of the Pneumatic press.
What other name can it receive?
- “air bag” press
- it consists of an horizontal cylinder with a bladder on one of the sides. Grapes are loaded on one of the sides and, as the bladder inflates, they are pushed against the grates the other side
advantages and disadvantages of the pneumatic press
advantages - it can be flushed with inert gas - it can be programmed to exert different amounts of pressure disadvantage - high initial investment
Explain the mechanism of the basket press
Cylindric vertical basket in which the grapes are loaded. The pressure is applied from above .the juice/wine will run through the gaps of the basket and collected by a tray at the bottom of the press
Advantages and disadvantages of the basket press
advantages - gentler than the pneumatic press - lower investment disadvantage - is not enclosed - cannot be flushed with inert gas - can only be use with smaller batches - more labour intensive
What is the pomace ?
the solid remains of grapes after pressing
Options when clarifying a white must
- sedimentation
- centrifugation
- flotation
- pectinolytic enzymes
Options when clarifying wine
- Sedimentation
- centrifugation
- Finning
Explain sedimentation
The wine/must is placed in a tank and chilled, to avoid oxidation/spoilage, and left to let the solid particles in suspension settle by gravity. Then is is racked to another tank and the sediments are left behind
The rate depends on the size and shape of the vessel
Explain Centrifugation
The must/wine is rapidly rotated by a centrifuge, a machine that uses centrifugal forces to separate liquid from solids.
It is very quick and efficient, but very costly in terms of equipment
It also increases O2 exposure, unless it is flushed with inert gas (further increasing costs).
It can be used continuously, reducing time and labour demand
What is Flotation? When can it be used?
- A technique for clarifying white musts, it cannot be used in final wines
- It involves bubbling gas through the must. as bubbles rise, they catch and bring solid particles with them, which are skimmed off the top of the vessel.
- Nitrogen is traditionally used, but O2 can also be used to hyper-oxidise the wine at the same time.
- It is most effective when a fining agent is used.
- It is fast, it can be carried out continuously, no chilling is needed. But initial investment on equipment is required, as well of the ongoing gas cost
How do the pectinolytic enzymes act? When can they be used?
- They break down pectin contained in cell walls of the plants/fruits. This allows a quick separation between the solids and liquids.
- it can only be used when clarifying must.
What is hyper-oxidation? How is it carried out?
- The deliberate oxidation of the must before fermentation. It is carried out to destroy and precipitate the most fragile components of the wine, resulting in a final wine that is more stable towards oxygen.
- A special tank is needed in which O2 is bubbled from the bottom of the vessel
What does the term “enrichment” refer to?
What are the different options?
- it refers to a range of practises/processed carried out to increase the concentration of sugar in the must, in order to achieve a higher alcoholic strength in the final wine.
- Options: adding dry sugar, grape must or CRGM; vacuum distillation, cryo-extraction, reverse osmosis.
What does de-acidification process consist of?
- achieved by the addition of a Carbonate (calcium or potassium) which neutralises acids
- it only has effect on tartaric acid, not in the harsher malic acid
- sometimes a small batch is completely neutralised, and then blended back to the bulk
Why are “nutrients” sometimes added to the must?
What products can be added?
- to increase nitrogen levels in the must, so that yeast can carry out a sound fermentation and avoid the synthesis of sulfur off-odours.
- Options: DAP, Thiamine
As well as acohol, CO2 and heat, what else do yeast produce during fermentation?
- SO2
- acetic acid
- aroma compounds
- glycerol
- higher alcohols
In what conditions do yeast produce ethanol? How are those conditions achieve in wine fermentation?
- in anaerobic conditions
- this is quickly achieved as the Dissolved oxygen is absorbed by the growing population of yeast. Which is required to their reproduction
What does “killer” yeast refer to ?
Yeast strains that produce compounds that poison other strains
Common species of ambient yeast
- Kloeckera
- Candida
Advantages of using wild yeast
- no cost
- marketing tool
- yeast are unique to the vineyard/winery
- more complexity in aroma compounds
Disadvantages of using wild yeast
- fermentation starts slowly
- fermentation to dryness takes longer
- increased risk of stuck fermentation
- consistent product cannot be guaranteed
Advantages of using cultured yeast
- reliable fermentation to dryness
- consistency
- ability of selecting specific strains for the style of wine being produced.
- low levels of VA
Disadvantages of using cultured yeast
- cost
- consistency in fruit expression may limit terroir expression
What temperature range is considered to be a “cool fermentation”?
Which styles of wines are produced at this fermentation temperature?
- 12-16C
- fresh fruity white wines
What temperature range is considered to be a “mid-range fermentation”?
Which styles of wines are produced at this fermentation temperature?
- 17 - 25C
- fruity early-drinking reds
- less fruity whites at the lower end
- barrel fermented whites at the higher end
What temperature range is considered to be a “warm fermentation”?
Which styles of wines are produced at this fermentation temperature?
- 26 - 32C
- more intense flavoured reds - more tannin and colour extraction but less fruity aromas retained.
advantages of using stainless steel tanks
- inert and airtight
- easy to clean
- high level of mechanisation is possible
- easy to control the fermentation temperature
- come in a variety of shape and sizes
Advantages of using concrete vessels
- high thermal inertia
- neutral and airtight
- can be build in-situ, according to the winery’s needs
Adv. and disadvantages of fermenting wines in wooden vessels
adv.
-retains heat
- gradual and controlled O2 exposure
-better integration of oak during maturation
dis.
- high cost
- difficult to clean, impossible to sanitise, pores my harbour spoilage microorganisms
what conditions are necessary to encourage MLF ?
- low total SO2
- moderated pH (3.3 - 3.5)
- Temperature between 18 - 22C
ways of preventing MLF
- adding SO2
- chilling the wine under 15C
- sterile filtration
- adding the enzyme lysozyme
what is the outcome of Malolactic conversion ?
- part of malic acid is converted to lactic acid
- reduction of acidity and rise in pH
- CO2 is produced
- colour loss in reds
- greater microbiological stability
- modification of flavour - lower fruitiness, more VA, production of diacetyl
What are the advantages of carrying out MLF in barrel?
- better integration of flavours
- use of lees to improve mouthfeel
What does the term “co-inoculation” refer to?
- inoculation of yeast and bacteria to carry out AF and MLF at the same time.
- sometimes bacteria is added half-way through AF or just before the end of it
what are the benefits of co-inoculation?
- improved retention of fruity aromas
- reduction of production times
- reduction in labour for monitoring two separated processes
- reduction of critical time in which the wine is exposed to spoilage organisms
Post fermentation adjustment options
- reduction of alcohol
- acidification and pH adjustment
- tannin addition
Ways of removing alcohol after AF
- Reverse osmosis
- spinning cone
What is the common path after AF for young fruity or acidic styles of wine
reductive techniques: - maturation is stainless steel - kept at low temperature - vessels blanketed with inert gas - also likely to be bottled shortly after AF -
Benefits of storing the wine in bulk
- more efficient use of store area
- flexibility to sell the wine according to market demand
- extended shelf life for young wines
- option of transporting in bulk to the final market, reducing cost of transportation
key factors in the maturation process
- oxygen exposure rate
- type of wood
- yeast lees
- temperature
How does temperature affect the maturation process of the wines ?
it determines which reactions take place, and at which rate.
Role of Oxygen during maturation
- improves colour stability in red wines
- gradual reduction of primary aromas, and development of tertiary aromas
- polymerisation of tannins and reduction of bitterness
- whites will turn darker, becoming golden and then brown
- reds become paler and turn from ruby to garnet and then tawny
how does wine get exposed to oxygen during barrel maturation?
- some O2 is released from the vessel the first month it is filled
- Small amount passes through the gaps between the staves and the pores of the wood
- the wine is most exposed with the bung is removed
Why do wooden vessels need to be topped up during maturation?
What factors increase the regularity in which they have to be topped up?
- some water and alcohol impregnate the wood
- then there is further loss as they diffuse to the outside and evaporate
evaporation rate is increased by - low humidity levels in the atmosphere
- smaller vessels
Why does the wine “concentrate” when it is subjected to long maturation periods in barrels?
Because water and alcohol evaporate through the pores of the oak. If humidity levels are low (less than 70%) water is lost at a higher rate, and the final wine will have a higher alcoholic strength.
Explain reverse osmosis process to reduce alcohol level of a wine.
- to revert the natural osmosis direction the more concentrated solution is subjected to high pressure.
- carried out in a cross-flow filter
- as the wine passes through, a mixture chiefly composed of water, acetic acid and alcohol is removed.
- alcohol is removed by distillation or another membrane process, and the water blended back to the wine.
What are the uses of reverse osmosis in winemaking?
- removing water from must (must concentration)
- removing VA from wine
- removing alcohol from wine
- removing 4-ethylphenol from wine