d-Block Flashcards

1
Q

Sc3+

A

Colourless

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2
Q

Ti4+

A

Colourless

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3
Q

Ti3+

A

Purple

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4
Q

V4+

A

Blue

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5
Q

V3+

A

Green

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6
Q

V2+

A

Violet

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7
Q

Cr3+

A

Violet

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8
Q

Mn3+

A

Violet

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9
Q

Cr2+

A

Blue

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10
Q

Mn2+

A

Pink

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11
Q

Fe3+

A

Yellow

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12
Q

Fe2+

A

Green

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13
Q

Co3+

A

Blue

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14
Q

Co2+

A

Pink

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15
Q

Ni2+

A

Green

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16
Q

Cu2+

A

Blue

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17
Q

Zn2+

A

Colourless

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18
Q

Highest Melting Point in 3d

A

Cr

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19
Q

Lowest Melting Point in 3d

A

Lowest 3d element -> Zn
Lowest transition element -> Mn

20
Q

Highest Melting Point in d-block

21
Q

Lowest Melting Point in d-block

22
Q

Highest Enthalpy of atomisation in 3d

23
Q

Lowest Enthalpy of atomisation in 3d

24
Q

Highest density in 3d

A

Cu >Ni (8.9 gcm-3)

25
Q

Lowest density in 3d

A

Sc (3.1 gcm-3)

26
Q

Highest density in d-block

27
Q

Lowest density in d-block

28
Q

Lowest I.E in 3d

29
Q

Highest I.E in 3d

30
Q

Group 12 I.E trend

A

Hg > Zn > Cd

31
Q

Highest Oxidation state

A

+8
Os, Ru, Xe

32
Q

Reduction Potential Eo M2+/M trend of 3d

A

Ti2+ < Mn2+ < V2+ < Cr2+ < Zn2+ < Fe2+ < Co2+ < Ni2+ < Cu2+

33
Q

Reduction Potential Eo M3+/M2+ trend of 3d (only the ones with +ve value)

A

Co3+ > Mn3+ > Fe3+

34
Q

Catalyst of Contact Process of Sulphuric Acid

35
Q

Catalyst of Ostwald Process of Nitric Acid

A

Pt / Rhodium

36
Q

Catalyst of Haber’s Process

37
Q

Catalyst of Alkene Hydrogenation

A

Wilkinson’s Catalyst
[Rh(PPh3)3Cl]

38
Q

Catalyst for Waker’s Process (Alkene->Aldehyde)

39
Q

Catalyst for Zieglar-Natta Polymers

A

TiCl4 + Et3Al
(Stannic Chloride + TriEthyl Aluminium)

40
Q

Brass is Alloy of

41
Q

Bronze is alloy of

42
Q

UK Silver Coins are made of

A

Cu+Ni Alloy

43
Q

UK Bronze Coins are made of

A

Copper Coated Steel

44
Q

Photography Industry uses

A

AgBr (Light Sensitive)

45
Q

Dry Cell Cathode is

46
Q

Pigment Industry uses

A

TiO (White Pigment)