d-Block Flashcards
Sc3+
Colourless
Ti4+
Colourless
Ti3+
Purple
V4+
Blue
V3+
Green
V2+
Violet
Cr3+
Violet
Mn3+
Violet
Cr2+
Blue
Mn2+
Pink
Fe3+
Yellow
Fe2+
Green
Co3+
Blue
Co2+
Pink
Ni2+
Green
Cu2+
Blue
Zn2+
Colourless
Highest Melting Point in 3d
Cr
Lowest Melting Point in 3d
Lowest 3d element -> Zn
Lowest transition element -> Mn
Highest Melting Point in d-block
W
Lowest Melting Point in d-block
Hg
Highest Enthalpy of atomisation in 3d
V
Lowest Enthalpy of atomisation in 3d
Zn
Highest density in 3d
Cu >Ni (8.9 gcm-3)
Lowest density in 3d
Sc (3.1 gcm-3)
Highest density in d-block
Os > Ir
Lowest density in d-block
Sc
Lowest I.E in 3d
Sc
Highest I.E in 3d
Zn
Group 12 I.E trend
Hg > Zn > Cd
Highest Oxidation state
+8
Os, Ru, Xe
Reduction Potential Eo M2+/M trend of 3d
Ti2+ < Mn2+ < V2+ < Cr2+ < Zn2+ < Fe2+ < Co2+ < Ni2+ < Cu2+
Reduction Potential Eo M3+/M2+ trend of 3d (only the ones with +ve value)
Co3+ > Mn3+ > Fe3+
Catalyst of Contact Process of Sulphuric Acid
V2O5
Catalyst of Ostwald Process of Nitric Acid
Pt / Rhodium
Catalyst of Haber’s Process
Fe
Catalyst of Alkene Hydrogenation
Wilkinson’s Catalyst
[Rh(PPh3)3Cl]
Catalyst for Waker’s Process (Alkene->Aldehyde)
PdCl2
Catalyst for Zieglar-Natta Polymers
TiCl4 + Et3Al
(Stannic Chloride + TriEthyl Aluminium)
Brass is Alloy of
Cu+Zn
Bronze is alloy of
Cu+Ti
UK Silver Coins are made of
Cu+Ni Alloy
UK Bronze Coins are made of
Copper Coated Steel
Photography Industry uses
AgBr (Light Sensitive)
Dry Cell Cathode is
MnO2
Pigment Industry uses
TiO (White Pigment)