D and F block Flashcards
why ‘d’-block elements are called transition elements
because of unpaired electron d-block elements can show transition from one energy level to another energy level
why zn/cd/hg are not considered as transition element
because of lack of unpaired electron
what is oxoanion
a molecule containing metal/non metal with oxygen and -ve charge on oxygen
electronic config.
d block —Ns2(n-1)d 1 to 10
-n=min is 4
physical properties of d-block
as d-block element are metallic in nature ,they show malleability, ductility, sonorus lusture
and all transition elements has strong metallic bonding due to unpaired electron
why transition element has high enthalpy of atomization
because of strong metallic bonding due to unpaired electron
why cr is the hardest metal in 3d series
due to the strongest metallic as max no. of unpaired electron
catalytic property
D-BLOCK elements acts as a good catalyst because of variable oxidiazation STATE that they can reduse as well as oxidise in the same process
complex formation
d-block element can form complexes because
-they have vacant outermost orbitals where ligands can donate their lone pair ND Form dative bond
reducing property
which reduces other and oxidizes itself in the same process
increase in oxidation no.
decrease in oxidation
size
across the period ,size decrease due to increase in effective nuclear charge
ionization POTENTIAL
across the period in 3d series I.P increses upto mn and almost remain same upto cu and slight decrease in I.P
observed due to same size
alloy formation
it is homogeneous mix of two or more than 2 metals and non metals