Cyclic Voltammetry Flashcards

1
Q

at equilibrium, reduction rate =

A

oxidation rate

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2
Q

what kind of solution is associated with chronoamperometry

A

unstirred solution

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3
Q

in chronoamperometry, diffusion from bulk solution brings current where

A

to electrode surface where reduction occurs

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4
Q

in chronoamperometry, with time current reduces because

A

decrease in current brought to electrode

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5
Q

amperometry is with what kind of solution

A

stirring

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6
Q

in amperometry, current is measured with what at what

A

WE at constant potential

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7
Q

current is proportional to what

A

concentration

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8
Q

current measures what

A

the rate of the reaction

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9
Q

Ampere is an electric current of what

A

1 coulomb per second

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10
Q

in a reversible system peak current is proportional to

A

square root of scan rate

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11
Q

in a reversible system, peak position does or does not depend on scan rate

A

does not

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12
Q

in a reversible system, cathodic current =

A

anodic current

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13
Q

in a quasi reversible system diffusion is

A

slow

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14
Q

in a quasi reversible system, peak current is proportional to

A

square root of scan rate

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15
Q

in a quasi reversible system, does peak position depend on scan rate

A

does

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16
Q

in quasi reversible system, diffusion occurs

A

fast

17
Q

what is anodic stripping voltammetry

A

analyte from a dilute solution is concentrated on a thin film or mercury by electroreduction and then stripped by reversing the potential