Cyclic Voltammetry Flashcards
at equilibrium, reduction rate =
oxidation rate
what kind of solution is associated with chronoamperometry
unstirred solution
in chronoamperometry, diffusion from bulk solution brings current where
to electrode surface where reduction occurs
in chronoamperometry, with time current reduces because
decrease in current brought to electrode
amperometry is with what kind of solution
stirring
in amperometry, current is measured with what at what
WE at constant potential
current is proportional to what
concentration
current measures what
the rate of the reaction
Ampere is an electric current of what
1 coulomb per second
in a reversible system peak current is proportional to
square root of scan rate
in a reversible system, peak position does or does not depend on scan rate
does not
in a reversible system, cathodic current =
anodic current
in a quasi reversible system diffusion is
slow
in a quasi reversible system, peak current is proportional to
square root of scan rate
in a quasi reversible system, does peak position depend on scan rate
does