Current Biomaterials Flashcards
Four types of biomaterial the body responds to
- Biotoxic
- Bioinert
- Bioactive
- Bioresorbable
Biotoxic - material and reaction
Materials: cadmium, vanadium, carbon steels, carbides
Reaction: atrophy, pathological change or rejection of living tissue
Bioinert - material and reaction
Material: tantalum, titanium, aluminium oxide and zirconium oxide
Reaction: Coexistence of material without noticeable change, separation from material by layer of fibrous tissue
Bioactive - material and reaction
Material: high density hydroxyapapatite, calcium phosphates, some bioglasses
Reaction: formation of biochemical bonds with surface of material and free growth
Bioresorbable - material and reaction
Material: tricalcium phosphate, porous hydroxyapapatite, some bioglasses
Physical properties of metals
- properties of bone implants
Metals:
- positive ions surrounded by sea of free electrons
- can conduct heat and electricity
- non directional bonds - plastically deformable
Bone implants:
- strong to support loads of bone
- ductile to avoid catastrophic failure - failure won’t happen as quickly as brittle fracture
- material can be replaced during failure process
- malleable to be machines easily
Polymers characteristics
- cheap
- lightweight
- easy to shape
- flexible and tough
- resistant to chemical attack
- low stiffness and strength - E = 1GPa
- high coefficient of thermal expansion
- degrade when exposed to uv light and oxygen
Homopolymer
Copolymer
Homo: Consists of one type of monomer unit
Co: Made up of more than one type of monomer unit
Thermoplastic vs thermoset
- thermoplastic can be heated, cooled and reshaped without changing chemical structures - melt at high T
-amorphous and semicrystalline - thermoset is irreversibly cured
- amorphous
Amorphous vs crystaline polymers
Amorphous have random orientation of polymer chains whereas crystaline polymers form highly ordered crystal structures within amorphous matrix
Ceramics
- definition, characteristics
- Ceramics are solid inorganic compounds with various combinations of ionic or covalent bonding
- more complex crystal structures than metals
- highly inert
- hard and brittle
- high compressive strength
- good insulators
Light
Physical properties of ceramics
- high melting points
- chemically stable at high temperatures
- high elastic modulus
- high hardness
- brittle
- sensitive to microcracks
- high compressive strength