Crystallography Flashcards
crystal =
lattice+motif
arrangement of atoms at each lattice point
motif / basis
lattice
An infinite periodic array of points in space with each point having identical surroundings.
primitive unit cell
contains single lattice point
Bravais lattices
are the distinct lattice types generated by the discrete translation operations given by:
r=ka+lb+mc
2D bravais lattices
5: oblique-p lattice, rectangular - lattice, rectangular c-lattice, square-p lattice, hexagonal-p lattice
3D Bravais lattices: Lattice centerings
P- primitive I - body centered F - Face centered A,B,C - base centered R - rhombohedral
3D Bravais lattices
Cubic: a=b=c α=β=γ=90°
Simple Body-Centered Face-Centered
P I F
Tetragonal a=b≠c α=β=γ=90°
Simple Body-Centered
P I
Orthorhombic
a≠b≠c α=β=γ=90°
Simple Body-Centered Base-Centered Face-Centered
P I C F
Rhombohedral (trigonal) a=b=c α=β=γ≠90°
Simple
P
Hexagonal a=b≠c α=β=90°, γ=120o
Simple
P
Monoclinic a≠b≠c α=γ=90°≠β
Simple Base-Centered
P C
Triclinic a≠b≠c α≠β≠γ≠90°
Simple
P
Miller indices
define families of directions
Direction
Determine the length of the projections of the direction on the three axes of the unit cell dimensions.
Reduce to smallest integers by dividing by a common factor.
square bracket
miller indices for single direction
miller indices for single direction bracket
square [ ]
set of families of directions
set of families of directions
distance between planes
lattice spacing