Crystal Systems Flashcards
Isometric
a=b=c
All axes @90 degrees
three 4-fold, four 3-fold
Hexagonal
a1=a2=a3
Intersecting @ 120 degrees, c perpendicular to plane
one 6-fold, two 2-fold
Tetragonal
a=b not=c
Alpha, Beta, Gamma = 90 degrees
one 4-fold, two 2-fold
Orthorhombic
a not=b not=c
Alpha, Beta, Gamma = 90 degrees
three 2-fold
Monoclinic
a not=b not=c
Alpha & Gamma = 90 degrees, Beta>90 degrees
one 2-fold
Triclinic
a not=b not=c
Alpha, Beta, Gamma not= 90 degrees
No symmetry
Alpha
Angle between b and c
Beta
Angle between a and c
Gamma
Angle between a and b
Unit Cell
Smallest unit of a structure, fits integral number of formula units, each corner identical, symmetry expressed at the atomic level.
Miller Indices Steps
1) Determine intercepts
2) Take reciprocals
3) Multiply by their common number
4) Clear fractions
Pedion
Open
Single face
Pinacoid
Open
Two parallel faces
Dome
Open
Two non parallel faces with mirror plane between
Sphenoid
Open
Two nonparallel faces with two-fold rotation axis