Crystal structure I Flashcards

1
Q

What is crystalline material?

A

Material where atoms are arranged in a repeating array, and
exhibit long-range order

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2
Q

What is crystal structure? What does it govern and what types of materials do they exist in?

A

the spatial arrangement of atoms in crystalline solids
* Governs material properties
* Exists in metals, many ceramics and some polymers

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3
Q

What is crystal morphology

A

shape and size of crystals or grains (e.g. coarse,
elongated or columnar, equiaxed, fine)

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4
Q

What is the unit cell?

A

The repeating entity that defines the structure
in a crystalline solid

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5
Q

What are the characteristics of the unit cell?

A

-Number of atoms per unit cell

-Coordination number

-Close packed directions

-Atomic packing factor

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6
Q

What is coordination number?

A

The number of nearest-neighbor or
touching atoms in a crystal structure

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7
Q

What are close-packed directions?

A

Directions within the unit cell with
highest linear density of atoms

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8
Q

What is the atomic packing factor?

A

The volume of atoms in a unit cell per
volume of a unit cell

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9
Q

Define density

A

ρ = mass per unit volume (kg/m3
)

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10
Q

What is theoretical density?

A

ρTh = mass of atoms in unit cell per
volume of unit cell

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11
Q

What type of properties does each phase or crystal structure have?

A

Mechanical, thermal, and electrical properties.

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12
Q

What properties change as iron changes between BCC (body centered cubic) and FCC (face centered cubic) structure?

A

Increasing temperature, with corresponding
changes in atomic packing densities
and corresponding stiffness (Young’s
modulus)

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13
Q

What mechanical properties do bond strength and crystal structure affect?

A
  • Modulus of Elasticity
    (Young’s modulus)
  • Resilience
  • Yield Strength
  • Ultimate Tensile Strength
  • % elongation
  • % reduction in area
  • Toughness
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14
Q

What is the number of atoms per unit cell for the BCC structure?

A

2 atoms per unit cell

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15
Q

What is the coordination number for the BCC structure?

A

8

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16
Q

What is the number of atoms per unit cell for FCC?

A

4

17
Q

What is the coordination number for the FCC structure?

A

12

18
Q

What is the number of atoms per unit cell for the HCP structure?

A

6 atoms per unit cell

19
Q

What is the coordination number for the HCP structure?

A

12

20
Q

What are the three-unit cells discussed in class?

A

BCC, FCC, and HCP.

21
Q

What are the close packed directions in a BCC unit cell?

A

The cube
diagonals

22
Q

Where are the close packed directions in a FCC unit cell?

A

Along the
diagonals of the cube faces

23
Q

What are the close packed directions for HCP?

A

Along the diagonals of the hexagonal face

24
Q

Name examples of metals that have the BCC crystal structure.

A

Chromium, iron (α, below
910 0C), molybdenum,
tantalum

25
Q

Name examples of FCC crystal structure.

A

Copper, aluminum, silver,
gold

26
Q

Name examples of the HCP crystal structure.

A

Cadmium, cobalt,
titanium (α), zinc