Cr 7 - Bonding and Organic Chemistry Flashcards

1
Q

What determines the structure of the periodic table?

A

The electron configurations of atoms determine the periodic table’s structure, grouping elements with similar valence electron arrangements and chemical properties.

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2
Q

How are elements classified in the periodic table?

A

Elements are classified as metals or non-metals based on their physical and chemical properties.

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3
Q

What are the common ionic charges for Groups 1, 2, 17, and 18?

A

Group 1: +1; Group 2: +2; Group 17: -1; Group 18: 0 (noble gases are inert).

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4
Q

What are the reactivity trends in periods 2 and 3 and groups I, II, and VII?

A

Reactivity varies across periods and groups; for example, Group I metals become more reactive down the group, while Group VII non-metals become less reactive down the group.

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5
Q

How does electron configuration explain an atom’s ability to form chemical bonds?

A

Electron configuration determines the number of valence electrons, influencing how atoms bond to achieve stable electron arrangements.

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6
Q

How does bonding type affect a substance’s physical properties?

A

The type of bonding (ionic, covalent, metallic) influences properties like melting point, conductivity, and hardness.

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7
Q

What are the characteristics of ionic compounds?

A

Ionic compounds have high melting points, are brittle, and conduct electricity when molten or in solution due to their crystalline lattice of oppositely charged ions.

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8
Q

How are ionic compounds named and their formulas determined?

A

By combining the names and charges of common cations and anions, ensuring the overall charge is balanced.

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9
Q

What explains the properties of metals like malleability and conductivity?

A

The properties of metals like malleability and conductivity are explained by metallic bonding, where positive metal ions are arranged in a regular lattice and surrounded by a “sea” of delocalised (free-moving) electrons.

These mobile electrons can move throughout the structure, allowing electricity and heat to be conducted easily.

The bonding is strong and multidirectional, meaning the electrostatic attraction between the positive ions and the delocalised electrons holds the structure together in all directions.

This allows the metal layers to slide over each other when force is applied, making metals malleable (able to be shaped without breaking).

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10
Q

How are covalent substances structured?

A

Covalent substances can form molecules or networks where atoms share electrons, resulting in strong intramolecular bonds and varying intermolecular forces.

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11
Q

What distinguishes intra- and intermolecular forces in covalent compounds?

A

Intramolecular forces are strong bonds within molecules; intermolecular forces are weaker attractions between molecules.

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12
Q

How is water an example of a polar covalent molecule?

A

Water has a bent shape with polar O-H bonds, leading to a net dipole moment and strong hydrogen bonding between molecules.

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13
Q

How does polarity affect melting and boiling points?

A

Polar molecules like water have higher melting and boiling points due to stronger intermolecular attractions.

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14
Q

How are covalent molecular compounds named from formulas?

A

Using prefixes to denote the number of atoms (e.g., CO₂ is carbon dioxide), based on the molecular formula.

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15
Q

What are the allotropes of carbon and their structures?

A

Diamond (3D tetrahedral network), graphite (layers of hexagonal lattices), and fullerenes (spherical molecules like C₆₀).

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16
Q

How can physical properties predict a substance’s structure?

A

Properties like melting point, conductivity, and hardness can indicate whether a substance has ionic, covalent, or metallic bonding.

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17
Q

How can specific ions in solutions be identified?

A

Using flame tests or chemical reactions that produce characteristic colors or precipitates.

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18
Q

How are precipitation reactions predicted?

A

By using solubility tables to determine if a combination of ions will form an insoluble compound.

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19
Q

What are overall and net ionic equations?

A

Overall equations show all reactants and products; net ionic equations show only the species that change during the reaction, omitting spectator ions.

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20
Q

How are H₂, O₂, and CO₂ gases identified?

A

Through simple gas tests: H₂ pops with a flame, O₂ relights a glowing splint, CO₂ turns limewater milky.

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21
Q

How can unknown inorganic compounds be identified?

A

By analyzing their solubility and reactions with specific reagents.

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22
Q

What types of hydrocarbon compounds does carbon form?

A

Alkanes, alkenes, alkynes, cyclic alkanes, and cyclic alkenes.

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23
Q

How are organic compounds named using IUPAC nomenclature?

A

By identifying the longest carbon chain (up to 10 carbons) and applying prefixes/suffixes for branches and functional groups like F, Cl, Br, and I.

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24
Q

What is an isomer?

A

Compounds with the same molecular formula but different structural arrangements.

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25
What distinguishes saturated and unsaturated hydrocarbons?
Saturated hydrocarbons (alkanes) have single bonds; unsaturated hydrocarbons (alkenes, alkynes) have double or triple bonds.
26
What are empirical, molecular, and structural formulas?
Empirical: simplest ratio of atoms; Molecular: actual number of atoms; Structural: shows all atoms and bonds.
27
What reactions do alkanes undergo?
Complete and incomplete combustion; substitution reactions with halogens under UV light.
28
What reactions do alkenes undergo?
Addition reactions with H₂, halogens (X₂), and hydrogen halides (HX); test for unsaturation using bromine solution.
29
How does the bromine test indicate unsaturation?
Bromine solution decolorizes in the presence of unsaturated hydrocarbons due to addition reactions at double or triple bonds.
30
What is the structure of the periodic table based on?
The electron configuration of atoms.
31
How are chemical behaviour and reactivity patterns identified in the periodic table?
Through similarities and trends in periods and groups.
32
How are elements divided based on their general properties?
Into metals and non-metals.
33
Why are elements arranged into groups on the periodic table?
Because they have similar properties and common ionic charges.
34
What are the typical charges for Groups 1, 2, 17, and 18 (or I, II, VII, VIII)?
Group 1: +1, Group 2: +2, Group 17: -1, Group 18: 0 (noble gases).
35
What trend in reactivity is observed in Groups I and II?
Reactivity increases down the group.
36
What trend in reactivity is observed in Group VII (17)?
Reactivity decreases down the group.
37
What trend is seen in periods 2 and 3 in terms of reactivity?
Reactivity varies across the period; metals become less reactive and non-metals become more reactive across a period.
38
What determines an atom’s ability to form chemical bonds?
Its electron configuration.
39
What explains the physical properties of substances?
The type of bonding within them.
40
What are the three main types of bonding in substances?
Metallic, ionic, and covalent bonding.
41
What causes chemical bonds to form?
Electrostatic attractions due to electron sharing or transfer.
42
What does 'valency' mean?
The number of bonds an atom can form.
43
What are ions?
Electrically charged atoms or groups of atoms due to an imbalance of electrons and protons.
44
How are ions represented?
By their chemical formula showing number of atoms and charge, e.g., Ca²⁺, SO₄²⁻.
45
Why do ionic compounds have high melting points and brittleness?
Due to strong electrostatic forces in a crystalline lattice.
46
When can ionic compounds conduct electricity?
When molten or dissolved in solution.
47
How are ionic compounds named and their formulas found?
Using tables of common anions and cations.
48
What makes metals malleable and good conductors?
Metallic bonding: positive ions in a lattice with delocalised electrons.
49
What is a covalent bond?
A bond formed by sharing electrons between atoms.
50
How are covalent substances structured?
As molecules or covalent networks.
51
What’s the difference between intra- and intermolecular forces?
Intramolecular: strong bonds within molecules; Intermolecular: weaker forces between molecules.
52
What are electron dot diagrams used for?
To show bonding in molecules of elements and covalent compounds.
53
What makes water a highly polar covalent molecule?
Unequal sharing of electrons and molecular shape.
54
How does water’s polarity affect its physical properties?
Increases melting and boiling points.
55
How are covalent molecular compounds named from formulas?
Using prefixes (mono-, di-, tri-) and the element names.
56
What are some allotropes of carbon?
Graphite, diamond, and fullerenes.
57
Why do carbon allotropes have different properties?
Because of their different structures.
58
How can you predict a substance’s structure type?
By investigating its physical properties.
59
What are two techniques to identify ions in solution?
Flame tests and chemical reactions.
60
What tool helps predict products of precipitation reactions?
A solubility table.
61
What are spectator ions?
Ions that do not participate in the chemical reaction.
62
What gas tests are used to identify H₂, O₂, and CO₂?
H₂: pop test, O₂: relights glowing splint, CO₂: turns limewater cloudy.
63
How are unknown inorganic compounds identified?
By testing solubility and using flame/precipitation tests.
64
What types of hydrocarbons does carbon form?
Alkanes, alkenes, alkynes, cyclic alkanes and alkenes.
65
What naming system is used for organic compounds?
IUPAC nomenclature.
66
What is an isomer?
Compounds with the same molecular formula but different structures.
67
What’s the difference between saturated and unsaturated hydrocarbons?
Saturated: only single bonds; Unsaturated: includes double/triple bonds.
68
What are the three types of chemical formulae?
Empirical, molecular, and structural formulae.
69
How do you test for unsaturation in hydrocarbons?
Using bromine water – it decolorises if double/triple bonds are present.