Cp And Cv Flashcards
Explain heat capacity
dq/dt
System me jitney hum heat de rhe hai usse temperature Kitna increase ho rha hahi
To raise the temperature of the substance by 1k
Heat capacity is a
Path function
What is specific heat capacity
The amount of heat required to raise the temperature of 1gm substance by 1 degree
System ko heat hum kitne trike se de skte hai
At constant volume Cv
At constant pressure Cp
C=
dq/dt = TdS/dt
When we give heat to system at constant volume then change occur in
System internal energy
Cv = dqv/dT =dU/dt
dU=Cvdt
Jab heat system ko at constant pressure pr di jaa rhi hai tb change
Enthalpy me aata hai
Cp=dqp/dT =dH/dt
dH=CpdT
Which one is greater Cp OR Cv
Cp>Cv
Cp of liquid >Cp of solid
Cp -Cv
T[dp/dt]v. [dV/dT]p
1st thermodynamic state
[6U/6V]T
Change in internal energy with respect to volume at constant temperature
Internal pressure pi T
1st law of thermodynamic for ideal gas or real gas
For ideal [6U/dV]T = 0
For real [6U/6V]T = a/V²
2nd law of thermodynamic for ideal or real gas
6H/6P = O FOR IDEAL
6H/6P= b–2a/RT