Cosmochemistry Flashcards
what is an isotope
same number of protons, different number of neutrons
what are “magic” electronic configurations?
a nucleus is most stable when the proton or neutron shells are full and paired, making even numbers more energetically favorable than odd.
beta decay
emission of an electron by the nucleus, converts a neutron to a proton and increases Z by one without changing A
positron decay
converts a proton to a neutron, reduce Z by one without changing A
alpha decay
emission of an alpha particle (2 protons, 2 neutrons), decreases Z by two and A by four
quantum numbers
principle quantum number, n: effective volume of an orbital
angular momentum quantum number, l: shape of the region occupied by an electron
magnetic orbital quantum number, ml: orientation of the electron orbital relative to an arbitrary direction
magnetic spin quantum number, ms: describes the positive or negative point relative to an outside magnetic reference
pauli exclusion principle
each orbital contains two electrons with opposite spins
valence electrons
outermost unfilled shells of electrons surrounding the nucleus
ionic bond
between metal and non-metal by the electrostatic attraction between oppositely charged ions
cation/anion
donates, becomes positive / accepts, becomes negative
covalent bonds
sharing of electrons between atoms, high bond strength
metallic bonds
sharing of valence electrons among many atoms in a delocalized manor
equilibrium fractionation
partition isotopes without changes in conditions
kinetic fractionation
fast, incomplete, or unidirectional processes such as evaporation, diffusion, dissociation reactions, and biological reactions
basic process of nucleosynthesis
nucleosynthesis involves the burning of hydrogen and helium to create elements of higher mass.
H-R diagram
plot of stellar luminosity vs effective surface temperature. in the main sequence, stars are converting hydrogen to helium in the core
r-process
rapid neutron capture such that multiple neutrons can be captured before beta decay occurs
s-process
slow neutron capture on a time scale that is slow compared to the rate of beta decay. occurs in the agb stage in low and intermediate mass stars when the H shell is burning outward from the core
chondrite classification
type 3= pristine , unaltered
4-7 thermally equilibrated
1-2 aqueously altered
matrix material
fine-grained minerals that fill the space between chondrules. high porosity, permeable, especially susceptible to alteration
characteristics of aqueous alteration in meteorites
altered matrix material primarily consisting of serpentine, sulfates/carbonates, iron altered to magnetite, no chondrules
characteristics of primitive meteorites
glassy chondrule mesostatsis in tact (alt crystallizes mesostasis into feldspar), CaO/FeO concentrations in olivine, chondrule boundaries are sharp, sulfides have low Ni contents, pyroxene is dominantly monoclinic