core organic chemistry Flashcards

1
Q

what is a functional group?

A

part of the organic molecule that is largely responsible for the molecule’s chemical properties

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2
Q

what is a hydrocarbon?

A

a compound containing carbon and hydrogen only

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3
Q

what is a homologous series? (2)

A

1) a family of compounds with similar chemical properties
2) whose successive members differ by the addition of a CH2 group

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4
Q

why does carbon form a large number of compounds? (3)

A

1) each carbon atom can form four covalent bonds
2) carbon atoms can bond to other carbon atoms to form long chains
3) bonds can be single, double or triple

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5
Q

what is a saturated hydrocarbon?

A

has single bonds only

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6
Q

what is an unsaturated hydrocarbon?

A

contains carbon-carbon multiple bonds

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7
Q

why is IUPAC important?

A

chemists across the globe can communicate early

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8
Q

what 3 groups can hydrocarbons the classified as? (3)

A

1) aliphatic- carbon atoms are joined to each other in unbranched (straight) or branched chains
2) alicyclic- carbon atoms are joined to each other in ring/ cyclic structures
3) aromantic- some or all of the carbon atoms are found in a benzene ring

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9
Q

what are the three homologous series of aliphatic hydrocarbons? (3)

A

1) alkanes- containing single carbon to carbon bonds
2) alkenes- containing at least one double carbon to carbon bond
3) alkynes - containing at least one triple carbon to carbon bond

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10
Q

what does the stem of the name of a compound indicate?

A

the number of carbon atoms in the longest continuous chain in the molecule

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11
Q

what does the prefix of the name of a compound indicate?

A

indicates the presence of side chains or functional groups

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12
Q

what does the suffix of the name of a compound indicate?

A

indicate functional groups

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13
Q

what steps should you follow when naming alkanes? (4)

A

1) all alkanes have the suffix -ane
2) identify the longest continuous chain of carbon atoms/ parent chain and name it
3) identify any alkyl groups attached to the parent chain. name alkyl group and add as a prefix to the parent chain
4) add numbers before any alkyl groups to show the position of the alkyl groups on the parent chain

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14
Q

what is systematic nomenclature?

A

can be used to name organic compounds and therefore make it easier to refer to them

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15
Q

why are the alkanes important for nomenclature?

A

1) The alkanes provide the basis of the naming system
2) the stem of each name indicates how many carbon atoms are in the longest chain in one molecule of the compound

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16
Q

what are the stems used in naming for alkanes from 1 to 10?

A

1) meth-
2) eth-
3) prop-
4) but-
5) pent-
6) hex-
7) hept-
8) oct-
9) non-
10) dec-

17
Q

how do you name side chains in alkanes? (3)

A

1) If there are more than one of the same alkyl side-chain or functional groups, di- (for two), tri- (for three) or tetra- (for four) is added in front of its name
2) The adjacent numbers have a comma between them
3) Numbers are separated from words by a hyphen

18
Q

how do you name multiple side chains in alkanes?

A

1) If there is more than one type of alkyl side-chain, they are listed in alphabetic order

19
Q
A