Contact process Flashcards

1
Q

what is the contact process used in

A

the manufacture or sulfuric acid

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2
Q

what are the 2 conditions and catalyst used in stage 2 of the contact process

A

450℃
2atm
V₂O₅ - vanadium (V) oxide

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3
Q

describe stage 1

A

sulfur is oxidised to form sulfur dioxide

S +O₂ → SO₂

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4
Q

describe stage 2

A

sulfur dioxide is oxidised to sulfur trioxide

SO₂ + O₂ ⇌ SO₃

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5
Q

describe stage 3

A

sulfur trioxide is absorbed into a solution of 98% sulfuric acid to produce a thick liquid called oleum
SO₃ + H₂SO₄ → H₂S₂O₇

oleum is then added to water to produce concentrated sulfuric acid
H₂S₂O₇ + H₂O → 2H₂SO₄

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6
Q

why isn’t sulfur trioxide absorbed into water

A

the reaction will produce a fine mist/gas of sulfuric acid which will be hard to condense and it’s also dangerous

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7
Q

why is an optimum temperature of 450 degrees celsius used in stage 2

A
  • the reaction between sulfur dioxide and oxygen is exothermic and high temperatures favour the reverse reaction increasing the yield of reactants and a lower yield of products is produced
  • the higher the temperature the lower the yield
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8
Q

why are 2atm used in stage 2

A

a higher pressure will shift the position of equilibrium far to the right producing 96% sulfur trioxide and a mixture of toxic gases
- a higher pressure would increase problems of dealing with the corrosive mixture of gases

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