Contact process Flashcards
what is the contact process used in
the manufacture or sulfuric acid
what are the 2 conditions and catalyst used in stage 2 of the contact process
450℃
2atm
V₂O₅ - vanadium (V) oxide
describe stage 1
sulfur is oxidised to form sulfur dioxide
S +O₂ → SO₂
describe stage 2
sulfur dioxide is oxidised to sulfur trioxide
SO₂ + O₂ ⇌ SO₃
describe stage 3
sulfur trioxide is absorbed into a solution of 98% sulfuric acid to produce a thick liquid called oleum
SO₃ + H₂SO₄ → H₂S₂O₇
oleum is then added to water to produce concentrated sulfuric acid
H₂S₂O₇ + H₂O → 2H₂SO₄
why isn’t sulfur trioxide absorbed into water
the reaction will produce a fine mist/gas of sulfuric acid which will be hard to condense and it’s also dangerous
why is an optimum temperature of 450 degrees celsius used in stage 2
- the reaction between sulfur dioxide and oxygen is exothermic and high temperatures favour the reverse reaction increasing the yield of reactants and a lower yield of products is produced
- the higher the temperature the lower the yield
why are 2atm used in stage 2
a higher pressure will shift the position of equilibrium far to the right producing 96% sulfur trioxide and a mixture of toxic gases
- a higher pressure would increase problems of dealing with the corrosive mixture of gases