Constants + Chem equations Flashcards
what is Avogadro’s number?
6.022 x 10^23
What is Planck’s constant?
6.6 × 10^-34 m2 kg / s
What is the formula for the energy of a photon?
E = hf
E = h x (c / λ)
h = planck’s constant = 6.6 x 10^-34
B- decay, what occurs?
convert a neutron to a proton + an electron.
This is the most common
atomic number –> go up by 1
mass number –> stay the same
neutron number –> down by 1
B+ decay, what occurs?
convert a proton to a neutron and a positron
atomic number –> down by 1
mass number –> stay the same
neutron number –> up by 1
electron capture, what occurs?
capture an electron and combine it with a proton to form a neutron.
atomic number –> down by 1
mass number –> stay the same
neutron number –> up by 1
formal charge calculation?
FC = valence - 1/2 bonding - lone
list the order of IMF strengths
ion-ion > ion-dipole > Hydrogen bonding > dipole-dipole > D-ID > ID-ID (dispersion forces)
t or f, radius increases to bottom left, acidity increases to bottom right.
true
equation for the heat of a phase change and the heat not during a phase change?
q = ΔH phase change x n
q = mcΔT
C = c x m
gibbs free energy?
ΔG = ΔH - TΔS
T in kelvin like always
What is STP?
T = 273 K P = 1atm = 760 mmHg = 760 Torr
Volume of an ideal gas at STP?
22.4 L
what is Boyle’s Law?
Isothermal law for gases
when temperature is constant, PV=nRT
Volume varies with 1 / P
What is Charle’s Law?
Isobaric law for gases
When pressure is constant, PV = nRT
Volume varies with T
ΔG° = ? for
a. when considering equilibrium reactions
b. when considering redox reactions?
ΔG° = -RTlnk
ΔG° = -nFE°
what is Faradays constant?
96,500 Coulombs which is equal to the charge of 1 mole of electrons
Nernst equation?
We can take
ΔG = ΔG° + RTlnQ and plug in ΔG° = -nFE°
ΔG = -nFE + RTlnQ
(note its E not E° since we are now dealing with ΔG)
solve for E to get
E = E° + (RT / nF) lnQ
OFTEN RT/F = 0.06
E = E° + (0.06 / n) lnQ
elementary charge (e)?
1.6× 10-19 coulombs
Coulombs constant (k)?
9 x 10^9 Nm^2 / C^2
density of water?
1000 Kg / m^3
1g / cm^3
speed of light?
3 x 10^8 m/s
speed of sound?
340 m/s
threshold of hearing?
Io = 10^-12 W/m^2
gas constant?
0.08 L atm / mol K