conformers of cyclopentane (chair forms) Flashcards
planar conformation of cyclopentane has little angle strain, but considerable torsional strain due to
eclipsing C-H bonds
The envelope and half-chair conformers involve less
torsional strain and are of similar energy
Equilibration between envelope and half-chair conformers is
rapid
To achieve bond angles of 109.5º and minimize torsional
strain, cyclohexane adopts a_____ conformation
chair
In the chair conformation, all adjacent C–H bonds are
staggard
To draw a chair, start with
two parallel lines slanted to the right or left
The boat conformer is a
high-energy
structure containing eclipsing C–H bonds
The skew-boat relieves
some of the
torsional strain in the boat
* Both are considerably high
The hydrogen in cyclohexane chairs are
substituents) in a cyclohexane chair
can be divided into two groups