conformers of cyclopentane (chair forms) Flashcards

1
Q

planar conformation of cyclopentane has little angle strain, but considerable torsional strain due to

A

eclipsing C-H bonds

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2
Q

The envelope and half-chair conformers involve less

A

torsional strain and are of similar energy

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3
Q

Equilibration between envelope and half-chair conformers is

A

rapid

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4
Q

To achieve bond angles of 109.5º and minimize torsional
strain, cyclohexane adopts a_____ conformation

A

chair

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5
Q

In the chair conformation, all adjacent C–H bonds are

A

staggard

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6
Q

To draw a chair, start with

A

two parallel lines slanted to the right or left

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7
Q

The boat conformer is a

A

high-energy
structure containing eclipsing C–H bonds

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8
Q

The skew-boat relieves

A

some of the
torsional strain in the boat
* Both are considerably high

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9
Q

The hydrogen in cyclohexane chairs are

A

substituents) in a cyclohexane chair
can be divided into two groups

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