Condensation silicones Flashcards

1
Q

base paste

A
  • polydimethyl siloxane
  • colloidal silica or micro sized metal oxide filler:
    • putty viscosity 60-70%
    • medium viscosity 35-75 fillers
    • low viscosity 5-15
  • color pigments
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2
Q

base paste

A
  • polydimethyl siloxane
  • colloidal silica or micro sized metal oxide filler:
    • putty viscosity 60-70%
    • medium viscosity 35-75 fillers
    • low viscosity 5-15
  • color pigments
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3
Q

accelerator paste

A
  • alkyl silicate like orthoethyl silicate(cross-linking agent)
  • stannous octoate-catalyst
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4
Q

setting rxn

A
  • condensation rxn
  • crosslinking bet orthoethyl silicate and dimethyl siloxane
  • exothermic 1 deg increase
  • ethyl alchohol forms byproduct for shrinkage
  • 8-9 min
  • mixing 45 sec
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5
Q

advantages

A
  • adequate working and setting time
  • pleasant odor no staining
  • adequate tear strength
  • better elastic properties on removal
  • less distortion on removal
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6
Q

advantages

A
  • adequate working and setting time
  • pleasant odor no staining
  • adequate tear strength
  • better elastic properties on removal
  • less distortion on removal
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7
Q

accelerator paste

A
  • alkyl silicate like orthoethyl silicate(cross-linking agent)
  • stannous octoate-catalyst
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8
Q

setting rxn

A
  • condensation rxn
  • crosslinking bet orthoethyl silicate and dimethyl siloxane
  • exothermic 1 deg increase
  • ethyl alchohol forms byproduct for shrinkage
  • 8-9 min
  • mixing 45 sec
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9
Q

other characteristic

A
  • excellent detail reproduction
  • high curing shrinkage
  • permanent deformation 1-3%
  • tear strength: 3000 gm/cm lower than polysulfides
  • stiffer and harder than polysulfide
  • hydrophobic
  • electroplated w/ silver and copper
  • shelf life: less than 2 years
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10
Q

advantages

A
  • adequate working and setting time
  • pleasant odor no staining
  • adequate tear strength
  • better elastic properties on removal
  • less distortion on removal
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11
Q

disadvantages

A
  • adequate accuracy if poured immediately
  • poor dimensional stability
  • potential for significant distortion
  • slightly more expensive
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