Compounds And Chemical Bonds Flashcards
Why do some atoms bind to one another ?
To lower the energy of the valence electrons
-increased stability
-core electrons are unaffected by bonding
-most stable atoms have full valance shells
-noble gases,at end of each period -unreative
Define ionisation energy ?
Ionisation energy of an atom is the amount of energy required to remove an electron from an isolated atom into vacuum.
-Typically measured in kJ mol -1
- 1st IE = energy required to remove one valence electron
Ionisation energy across a group ?
Increases
1ST IE ?
?
Electronegativity ?
An atoms attraction for electrons in a bond
-smaller atoms have a greater attraction for their valence electrons
Electronegativity across ?
A group increases
Pauling Electronegativity ?
? Add
What is the key to chemical bonding ?
When atoms come together ,their electronegativities determine how they bond
Check online PowerPoint
The triangle of something ?
Insert picture
Ionic bonding ?
- Typically between metals and non metals
-main group ions (s & p block) have full valence shells
-Ions don’t exist in isolation- ionic compounds are electrically neutral
- the charges on ions cancel out
Examples of ionic compounds?
- Pure ionic compounds are usually solid at room temp and pressure
- main group ionic compounds are usually white
- dissolve in water to release ions
E.g:
What do pure ionic compounds contain ?
Extended lattice of ions
Which are held together by electromagnetic interactions
(Electrostatic or Colombic interactions)
What is pure covalent bonding ?
Pair of shared electrons
(Bonding electrons spend most of their time between the 2 nuclei)
-covalent bonding is also electrostatic
Eg) Lewis dot diagram
Such as dehydrogenate
Lewis structures for period 2,3
Have lone pairs or non bonding pairs
Most period 2 elements obey the octet rules(forming stable compounds (8))
However higher periods often disobey
-because bigger atomic sizing as group decreases -more space
-Period 3 - S,P,D -available all time in 3 shell
Calculating & why formal charge ?
Helps us to to check Lewis structures by assigning electrons to atoms
FC = number of valence electrons in isolated atom-(non bonding valence electrons + 1/2 bonding electrons)
Most of the time all FCs in a neutral molecule are zero