Composites Flashcards
Definition
and exampls
Material composed of two or more distinct phases whose combinatio produces aggregate properties that differ from original components
Examples: plastic moulding components with fillers, rubber mixed with black carbon, wood
Components
- Primary phase - forms matrix
- Secondary phase - imbedded sometimes referred to as a resinforcing agent as usually strengthens material
- can be in form of fibres, particles and other various geometries
Polymer Matrix
- Provides the bulk form of the part
o Holds the embedded phase in place (usually enclosing and often concealing it)
o When a load is applied, the matrix shared the load with the secondary phase, in some cases deforming so that the stress is essentially born by the reinforcing agent - Both thermoplastics and thermosets are used as matrices in PMCs
o Thermosetting polymers are the most common matrix material
Phenolics, unsaturated polyesters and epoxies
o Thermoplastics include nylons (polyamides), polycarbonate, polystyrene and polyvinylchloride
Reinforcement Phase
- Function is to reinforce the primary phase
- Reinforcing phase (imbedded in the matrix) is most commonly fibre, particle or flake shaped
- Fibres can be short or long (continuous or discontinuous), orientated or random
Fibre Reinforced Polymers (FRP) Examples
- Glass - most widely used
- Carbon - high elastic modulus
- Polymers - Kevlar 49
FRP Properties
- High strength-to-weight ratio (W=1/5 of steel yet stregnth and modulus comparabble in fibre direction)
- Good fatigue strength
- Good corrrosion resistance, although polymers are soluble in various chemicals
- Low thermal expansion for many FRPs
FRP Applications
- Aerospace
- Automotive
- Sports and recreation: boat hulls, fishing rods, tennis racquets, golf club shafts etc.
Processing of Polymer Matrix Composites
Open mould processes
- Manual lay up and spray up
- Automated lay up
Closed mould (similar to plastics moulding)
- Compression moulding
- Resin transfer moulding
Filament winding
Pultrusion processes
Combining Matrix and Reinforcement
- Materials arrive as seperate entities and are combined durig shaping
- Filament winding and pultrusion, in which reinforcing phase are continuous fibres - The two component materials are combined into some starting form that is convinient for shaaping
- Moulding compounds
- Prepregs
Moulding Compounds
- FRP composite compounds consist of the resin matrix with short randomly dispersed fibres, similar to those used in plastic moulding
- Most moulding compounds for composite processing are thermosetting polymers
- Since they are designed for moulding, they must be capable of flowing - cured during and/or after final shaping, not during shape processing
Open-mould Processes
Family of FRP shaping processes that use single positive and negative mould surface to produce laminated FRP structure
- Hand lay-up
- Spray-up
- Automated lay-up
Starting materials (resins, fibres, mats, woven rovings) are applied to the mould in layers
Followed by curing and part removal
Common resins are unsaturated polyesters and epoxies, using fibreglass as the reinforcement
Prepregs
- Fibres impregnated with partially cured TS resins to facilitate shape processing
- Curing is completed during and/or after shaping
- Fabricated with continuous filaments - increases strength and modulus
- Available in the form of tape or cross-plied sheets or fabrics
- Associated with advanced composites - Kevlar and fibreglass
- Typically stored in a freezre
Hand (Wet) Layup
- Shaping method in which successive layers of liquid resin and reinforcement are manually applied to an open mould
- Labour intensive
- Orientation of the fibres is controlled hence resulting in stronger products made by spray up
- Applications for large parts but low in production quantity - not economical for high production
Hand Lay-up Process
- Mould is treated with mould release agent
- Thin gel coat (resin) is applied to outside surface of mould
- Layers of resin and fibre mat or cloth are applied - when gel coat is partially set, each layer is rolled to impregnate the fibre with resin and remove air
Spray-up Process
- Liquid resin and chopped fibres are sprayed onto an open mould to build successive FRP laminations
- Represents an attempt oto mechanise the application of resin-fibre layers and reduce lay-up time
- Applications: boat hulls, bathtubs, shower stalls etc.
- Randomly orientated short fibres mean not as strong as those made by hand lay-up as continuous and directed