Composite Resin Flashcards
What are the different phases in CR?
- Organic phase
- Dispersed phase
- Interfacial phase
What does the organic phase consist of?
- Monomers, mainly BisGMA
- Viscosity controllers
- Inhibitors
- Thermochemical and photochemical initiators
- Accelerators
- Additional components
What are the properties of BisGMA?
- High viscosity
- Colourless liquid
- Undergoes extensive cross-linkage, making it harder than acrylic resin
- High molecular weight (hence, low volatility)
- Relatively low polymerisation shrinkage (5-6%)
What are the disadvantages of BisGMA?
- Radiolucent
- Polymerisation is inhibited by air
- Absorbs water and takes in stains
What is the purpose of viscosity controllers?
To improve the handling properties (by decreasing viscosity) of CR during mixing and insertion as BisGMA, the main monomer, is highly viscous
What is the inhibitor used in CR? What is its purpose?
Hydroquinone. To prevent premature polymerisation and ensure long shelf life.
What are the initiators in CR?
Photochemical: Camphorquinone
Thermochemical: Benzoyl peroxide
What is the accelerator used in CR?
Tertiary aromatic amine
What type of bipolar coupling agent is most commonly used in CR?
Silane coupling agent
What is the purpose of coupling agent?
- Serves as a stress absorber at the filler-matrix interface
- Allows adhesion of 2 dissimilar materials, filler and matrix
What are the factors that affect the physical and mechanical properties of CR?
- Filler fraction
- Degree of polymeristion
- Water sorption
- Coupling efficacy
What are the effects of underpolymerisation of CR?
- Excessive wear and softness
- Loss of retention, leading to breakage
- Decreased mechanical properties
- Increased solubility
- Increased susceptibility to stains
- Poor colour stability
What are the 2 principles of polymerisation shrinkage?`
Principle 1: CR pulls away from least retentive surface, leading to gap formation and cuspal deformation
Principle 2: Direction of shrinkage is towards light source for light-cured resins, towards centre of mass for auto-cured/chemical-cured resins
What is C factor and the significance of it?
C factor is the ratio of bonded surfaces to unbonded surfaces
Significance: The lower the c factor, the lesser the number of bonded surfaces, the lesser the contraction stress on adhesive bond
How does polymerisation shrinkage lead to post-op sensitivity?
Polymerisation shrinkage results in gap formation and cuspal deformation.
Gap formation allows for bacteria and fluid to penetrate into tooth, in the long run, possibly leading to pulpal inflammation and thus pain and sensitivity.
Cuspal deformation: Flexure of CR under occlusal load causes hydraulic pressure in tubular fluid to be transmitted to odontoblastic processes