Composite Materials Flashcards

1
Q

What are Composite Materials?

A

Composite materials are material systems made from two or more physically distinct phases.

These phases combine to create properties that are different from the individual components.

They are often stronger, lighter, or more durable than their individual parts

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2
Q

Examples of composite materials

A

Cemented carbide (WC with Co binder): Used for cutting tools due to its hardness (tungsten carbide) and toughness (cobalt binder).

Plastic molding compounds with fillers: Fillers like clay or wood flour can improve strength or reduce cost without compromising overall properties.

Rubber mixed with carbon black: Carbon black strengthens rubber and improves its elasticity, making it ideal for tires.

Wood: A natural composite where cellulose fibers provide strength and lignin acts as a binder.

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3
Q

Matrix

A

Term: Matrix
Description:
Continuous phase in a composite material.
Surrounds and binds the filler together.
Usually ductile, tough, and has a lower density than the filler.
Strength is typically lower than the filler.
Examples:
Thermoplastics (e.g., polyethylene, nylon)
Thermosets (e.g., epoxy, phenolic)

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4
Q

Filler

A

Term: Filler / Reinforcing Material
Description:
Dispersed phase in a composite material.
Often strong and stiff, with a low density.
Designed to improve the overall properties of the composite.
Examples:
Fibers: glass, carbon, aramid (Kevlar)
Particles: clay, wood flour, metal oxides

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5
Q

Matrix and Filler Interaction

A

The bond between the matrix and the filler is crucial for the performance of the composite.
A good interface transfers stress effectively between the two phases.
Bonding can be adhesive (chemical) or mechanical.

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6
Q

Benefits of Composites

A

Term: Composite Advantages
Description:
By combining materials, composites can achieve properties not possible with individual components.
Benefits include:
High strength-to-weight ratio
Improved stiffness and rigidity
Design flexibility
Corrosion resistance

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7
Q

Example - Fiberglass

A

Material: Fiberglass
Matrix: Polymer (e.g., epoxy)
Filler: Glass fibers
Properties: Strong, lightweight, good corrosion resistance

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8
Q

Advantages of Composites

A

High Strength-to-Weight Ratio
High Specific Strength
High Creep Resistance
High Tensile Strength at Elevated Temperatures
Improved Performance under Cyclic Loads
Impact Resistance and Damping
High Wear Resistance
Corrosion Resistance
Reduced Dimensional Changes with Temperature
Anisotropic Properties

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9
Q

Disadvantages (or limitations) of Composites

A

Material Costs: Raw materials for composites can be expensive compared to some metals.
Fabrication Difficulties: Manufacturing processes for composites can be complex and require specialized equipment, increasing production costs.
Repair Challenges: Repairing composite components can be more challenging and expensive compared to metals.
Statistical Variability: Properties of composites can exhibit some variation due to the manufacturing process, requiring careful quality control.
Temperature Limitations: Polymeric matrix composites typically have lower operational temperature limits compared to metal matrix composites.
Design Complexity: The anisotropic nature of composites requires careful design considerations to account for the directional properties.
Inspection and Testing: Inspecting and testing composites for damage or defects can be more complex compared to traditional methods used for metals.

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10
Q

Metal Matrix Composites (MMC)

A

Matrix: Metal (aluminum, magnesium, iron, cobalt, copper)
Reinforcement: Ceramic (oxides, carbides) or Metallic (lead, tungsten, molybdenum)
Examples: Al-SiC (silicon carbide), Al-Al2O3 (aluminum oxide)
Properties:
High strength
High stiffness
Abrasion resistance
Dimensional stability
High-temperature performance
Improved toughness (compared to pure metals)

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11
Q

Ceramic Matrix Composites (CMC)

A

Matrix: Ceramic
Reinforcement: Ceramic fibers
Example: Silicon carbide-silicon carbide (SiC-SiC)
Properties:
Excellent high-temperature performance
High wear resistance
High hardness
Brittleness (can be a limitation)

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12
Q

Polymer Matrix Composites (PMC)

A

Matrix: Polymer (thermoset or thermoplastic)
Thermoset: Epoxy, Unsaturated Polyester (UP)
Thermoplastic: Polycarbonate (PC), Polyvinylchloride (PVC), Nylon, Polystyrene
Reinforcement: Fibers (glass, carbon, steel, Kevlar)

Examples:
GFRP (fiberglass): Polyester or epoxy with glass fibers
CFRP: Polyester or epoxy with carbon fibers
KFRP: Polyester or epoxy with Kevlar fibers
Properties:
High strength-to-weight ratio
Good corrosion resistance
Design flexibility
Can be tailored for specific properties based on fiber type

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13
Q

Composites in Engineering Applications

A

Widespread Use: Composites are finding increasing use in various engineering applications due to their unique properties.

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14
Q

Applications in Specific Industries

A

Aerospace: Because of their high strength-to-weight ratio, composites are ideal for aircraft components like wings, fuselages, and control surfaces. This translates to lighter airplanes with improved fuel efficiency and performance.
Automotive: Composites are used in car bodies, hoods, spoilers, and other parts to reduce weight and improve fuel economy. They can also be used for high-performance components requiring strength and stiffness.
Pressure Vessels and Pipes: Composites offer superior corrosion resistance and can be lighter than traditional materials like steel, making them suitable for pipelines and pressure vessels in various industries.

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15
Q

What are Biomaterials?

A

Definition 1 (Hench & Erthridge, 1982): Materials used to create medical devices that replace or restore a bodily function in a safe, reliable, and cost-effective way, with minimal impact on the body.
Definition 2 (Bruck, 1980): Materials, both natural and synthetic, that come into contact with living tissues, blood, or fluids for prosthetic, diagnostic, therapeutic, or storage purposes. They should not negatively affect the body or its components.
Definition 3 (Williams, 1987): Non-living materials used in medical devices that interact with biological systems within the body.

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16
Q

What are the key points of biomaterials?

A

Biomaterials are used in a wide range of medical devices.
They should be safe, reliable, and affordable.
They should be compatible with the body and not cause harm.

17
Q

Why are Biomaterials Needed?

A

High Demand: Millions of people experience organ and tissue failure each year.
Treatment Costs: The annual cost of treating these conditions is estimated at $400 billion globally.
Limited Donor Organs: Transplantation, while potentially lifesaving, is limited by a shortage of donor organs.
Reconstruction Challenges: Reconstructing damaged tissues can be complex and may not always be fully successful.
Limitations of Mechanical Devices: Traditional mechanical devices used for support, like artificial joints, can have limitations in terms of long-term function and wear.

18
Q

Biomaterials offer a promising alternative to address these challenges by providing materials for:

A

Tissue engineering and regeneration
Development of advanced prosthetics and implants
Improved surgical procedures

19
Q

Biomaterials Evolution: A Shift in Goals

A

The field of biomaterials has evolved significantly over time, with a changing focus on the desired interaction between the material and the body.

20
Q

1st Generation Biomaterials (1950s onwards)

A

Goal: Bioinertness - The primary focus was on creating materials that were inert (non-reactive) within the body.
Approach: These were often “ad-hoc” implants, improvised by physicians using readily available materials like metals, plastics, and even natural materials like ivory or bone.
Success: Many successes were accidental, as the materials weren’t specifically designed for biocompatibility.
Examples: Gold fillings, wooden teeth, PMMA dental prostheses, steel/gold bone plates, glass eyes.

21
Q

2nd Generation Biomaterials (1980s onwards)

A

Goal: Bioactivity - The focus shifted towards materials that could interact more favorably with the body, promoting tissue growth and integration.
Development: Engineered implants were created through collaboration between physicians and engineers, leveraging advances in materials science.
Examples: Titanium alloy dental and orthopedic implants, cobalt-chromium implants, UHMW polyethylene for joint replacements, heart valves, pacemakers.

22
Q

3rd Generation Biomaterials (2000s onwards)

A

Goal: Tissue Regeneration - The focus is on bioengineered materials that actively promote tissue repair and regeneration.
Current Status: While still under development, this generation is starting to see some market presence.
Examples:
Tissue-engineered implants designed to stimulate tissue regrowth instead of replacement.
Resorbable bone repair cements.
Genetically engineered “biological” components.

23
Q

Biomaterial Requirements

A

Biomaterials need to meet various physical, chemical, and biological criteria to function effectively in the body.

Physical Requirements:

Match Tissue Properties: The material’s stiffness, strength, and other physical properties should be similar to the tissue it replaces to ensure proper functionality.
Examples: Hard materials for bones, flexible materials for blood vessels.
Chemical Requirements:

Biocompatibility: The material should not cause any adverse reactions with body tissues.
Non-toxicity: The material should not be poisonous or harmful to the body.
Biostability (for long-term implants): The material should not degrade or break down rapidly within the body, especially for long-term implants.

24
Q

Essential Features of Biomaterials

A

Absence of Carcinogenicity: The material should not cause or promote cancer.
Absence of Immunogenicity: The body’s immune system should not reject the material as foreign.
Absence of Teratogenicity: The material should not cause birth defects if used in pregnant women.
Absence of Toxicity: The material should not be poisonous or cause any systemic harm.

25
Q

Polymers

A

Drug Delivery System
Skin/cartilage
Heart valves

26
Q

Metals

A

Orthopedic screws/fixation
Dental Implants

27
Q

Ceramics

A

Bone replacements
Dental Implants

28
Q

Semiconductor Materials

A

Implantable Microelectrodes
Biosensors