Composite material Flashcards
Resin modified GIs, GI
hydrophobic (water based)
self-adhesive
no adhesive required
Compomers, Composite resin
hydrophobic (resin based)
Not self adhesive - requires adhesive
Dental composite matrix phase
continuous phase
- monomer resin
- initiators
dental composite dispersed phase
discontinuous phase
- glass fillers
- colorants
Monomer functional groups
monomethacrylates
dimethacrylates
monomethacrylates
linear chains - soft - can melt easily
dimethacrylates
branched and crosslinked - rigid, don’t melt easily.
Composite monomers
difunctional methacrylates
form highly crosslinked rigid networks
Monomers in composite
potentially estrogenic - tegma, BIS-GMA, TEGDMA
Silicate glasses influence
strengthen (rule of mixtures, more filler = more strength) Optical properties (color, translucency) Radiopacity
Filler surface
glass has hydrophilic surface
- silica tetrahedrons
- surface hydroxyl groups
- attract water molecules
- inhibits wetting of surface with monomers (hydrophobic)
Silane coupling agent
silane coupler - gets hyrophilic glass into composite
- improve composite properties
- adheres filler to resin phase
- primer
- MPS
Abrasive
non-contact wear - foods abrade polymer
Attrition
occlusal contact wear - higher stresses, lead to polymer microfracture
Improved wear from
smaller, softer particles