compomers ceromers ormocers 8 Flashcards
COMPOMERS Terminology
Polyacidmodified resin composites (COMP) Composites+ ionomers= compomers Dyract (Dentsply De Trey) -1993
COMPOMERS
Delivery mode
Monocomponent system (hermeticallysealed package,metallicfoils)
COMPOMERS
Composition
1.a.dimethacrylicorganicalmatrix+ b.acidgroups(carboxylicgroups) 2.filler(fluoridealumino-silicateglass) 1b+2=acid-basesettingreaction
COMPOMERS
Setting reaction
- main setting reaction–light-curing
- the acid component of the organical matrix can’t participate at the acid-base reaction, because there is no water between the components
- in the oral environmentwhile it uptakes water–>acid-base reaction(between the carboxylic and polyglasschains)
Differences between Differences between COMP COMP and and RMGIC
RMGIC–acid-base reaction starts immediately + lightlight–curing
COMP––lightlight–curing+ delayed acid–base reaction
comp properties mechanical
these materials were introduced in order to combine the mechanical and surface properties of the RBCs with the adhesive and F release of the GIC
1.Mechanicalproperties -mechanical strength >GIC andRMGIC ~RBC with microfiller -hardness≤ ≤≤ ≤RBCs -abrasion strength decreases in time due to acid attack against glass particles and due to acid-base setting reaction
comp surface properties
-much better than RMGICsand maintained intime
comp adhesive properties
similar adhesion as the RBCs–similar use of adhesive systems
comp carrioprophylactic effect
- in the oral environment–acid attack against the glass particles of F-Al-silicate=>it is released a certain amount of F-ions
- the time of F-ions release is reduced and there is no evidence that these materials reduce secondary decays
comp polymerization shrinkage
-similar to that ofRBCs, but =>the main part of the shrinkage is produced in the plastic phase and it can be compensated through creep -positive effect on the reduce of residual stress and on the marginal closure
comp water sorbtion
made
through the hydrophilic organical matrix, generally>than RBCs -it increases the F-ions release -used in big quantity–negative effect on the mechanical properties
comp handling features
non-sticky→ →→ →preferred comparing with RMGICs7
comp indications
- decidualteeth fillings
- special fillings for decidualteeth
- class V cavities and cervical erosions
- class I and II cavities
- class III cavities
- sealant agents
- bracketsfixing
subclasses of RBCs
•CEROMERS •ORMOCERS •POLYGLASSES
the ceromers
terms
composition
indications
Terms:
Resin composites which have inside inorganic filler, ceramic particles
Ceramic optimized polymer= ceromer i.e.Targis (Ivoclar), Tetric Ceram (Vivadent)
Composition: 1.dimethacrylicorganic matrix 2.80% of filler -5 types of particles -Baglass/ yttrebium trifluoride/ glass of AlFsilicate/ sillica/ oxides mixture
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INDICATIONS:
-class I, II, III, IV, Vcavities, cervical erosions
-polymeric or ceramic veneers repairs
-direct inlays/ onlay
!They need special (adapted) adhesive systems
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the ormocers
terms
composition
Term :
RBC with organic phase –>an inorganic -organic monomer
Organically modified ceramics= ormocer
i.e.Definite (Degussa) Admira (VOCO) -1999
Composition:
..organic phase : polysiloxane matrix with double curing bonds
2. inorganic filler
the ormocers
setting
properties
indications
Setting reaction The Si(OR)3group can form double bonds with the matrix’s monomers or with inorganic components of the filler=>polycondensed matrix(rich crosslinked)
Properties
•The molecular weight is1000x >than that of the RBCs’ monomers •Polymerization shrinkage with 50%
polyglasses
Terms:
Resin composites which after their polymerization have glass features;they are frequently used for indirect
restorations (made in the dental lab)
i.e. Artglass (Heraeus Kulzer) –1995; Belle-glass (Kerr) – 1996; Solitaire (Heraeus Kulzer) –1997
Composition: 1.organic matrix based on polyfunctional monomers - increased conversion rate of polymerization and chromatic stability 2. inorganic filler (65%) –mixture of glasses16
Selection criteria of the aesthetic direct restorative materials
advantages versusdisadvantages lateral zoneversus anterior zone
•Criteria: –longevity–mechanical and chemical properties –minimal loss of dental tissue–adhesion type/ preparation type –aesthetics–initially and in time 21