Complex/Inorganic Ion Colours Flashcards
[Cu(H2O)6]2+
from CuSO4.5H2O(s)
pale blue
Cu(OH)2(s)
NH3 dropwise to Cu2+(aq)
pale blue precipitate
[Cu(NH3)4(H2O)2]2+
excess NH3 to Cu2+(aq)
dark blue
CuCl42–
excess HCl to Cu2+(aq)
yellow
Cu+
reduction of Cu2+ with I–
white precipitate (cu) and brown solution (I)
Cu2+ / Cu
Disproportionation of Cu+
brown solid (Cu) and blue solution (CuSO4)
CoCl42–
from CoCl2.6H2O(s) plus water and excess HCl
blue
Cr(H2O)6]3+ from KCr(SO4 )2.12H2O(s)
pale purple
green when heated
impurities - could appear green
Cr(OH)3(s)
NH3 dropwise to Cr 3+(aq)
dark green precipitate
[Cr(NH3)6]3+
excess NH3 to Cr 2+(aq)
purple
[Cr(OH)6]3–
excess OH– to Cr(OH)3(s)
dark green
Cr2O72– from K2Cr2O7(s) in 0.1mol dm-3 H2SO4
orange
CrO42–
oxidation of Cr3+ with hot alkaline H2O2
yellow
[Mn(H2O)6]2+
from MnSO4.4H2O(s)
pale pink
Mn(OH)2(s)
NaOH dropwise to Mn2+(aq)
pale brown precipitate