Complex/Inorganic Ion Colours Flashcards

1
Q

[Cu(H2O)6]2+

from CuSO4.5H2O(s)

A

pale blue

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2
Q

Cu(OH)2(s)

NH3 dropwise to Cu2+(aq)

A

pale blue precipitate

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3
Q

[Cu(NH3)4(H2O)2]2+

excess NH3 to Cu2+(aq)

A

dark blue

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4
Q

CuCl42–

excess HCl to Cu2+(aq)

A

yellow

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5
Q

Cu+

reduction of Cu2+ with I–

A

white precipitate (cu) and brown solution (I)

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6
Q

Cu2+ / Cu

Disproportionation of Cu+

A

brown solid (Cu) and blue solution (CuSO4)

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7
Q

CoCl42–

from CoCl2.6H2O(s) plus water and excess HCl

A

blue

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8
Q
Cr(H2O)6]3+
from KCr(SO4 )2.12H2O(s)
A

pale purple
green when heated
impurities - could appear green

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9
Q

Cr(OH)3(s)

NH3 dropwise to Cr 3+(aq)

A

dark green precipitate

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10
Q

[Cr(NH3)6]3+

excess NH3 to Cr 2+(aq)

A

purple

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11
Q

[Cr(OH)6]3–

excess OH– to Cr(OH)3(s)

A

dark green

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12
Q
Cr2O72–
from K2Cr2O7(s) in 0.1mol dm-3 H2SO4
A

orange

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13
Q

CrO42–

oxidation of Cr3+ with hot alkaline H2O2

A

yellow

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14
Q

[Mn(H2O)6]2+

from MnSO4.4H2O(s)

A

pale pink

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15
Q

Mn(OH)2(s)

NaOH dropwise to Mn2+(aq)

A

pale brown precipitate

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16
Q

[Fe(H2O)6]2+

from FeSO4.7H2O(s)

A

pale green

17
Q

Fe(OH)2(s)

NaOH dropwise to Fe2+(aq)

A

dark green precipitate

18
Q

[Fe(H2O)6]3+

from FeCl3.6H2O(s)

A

yellow

19
Q

Fe(OH)3(s)

NaOH dropwise to Fe3+(aq)

A

orange-brown precipitate

20
Q

MnO4–/Fe2+ Mn2+/Fe3+

A

purple to pale pink

21
Q

I–/Fe3+ I2/Fe2+

A

orange-brown to brown