Common questions Flashcards

1
Q

relative molecular mass

A
  • the average mass of a molecule
  • compared to 1/12 of the mass of one atom of carbon-12
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2
Q

first ionization energy

A

the minimum energy required to remove the outermost electron from a neutral atom in gas phase

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3
Q

why are compounds of d-block coloured

A
  • unpaired electrons from the d orbitals split into 2 energy levels
  • electrons can transition between those states and absorb light of visible wavelengths
  • complimentary colour can be observed
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4
Q

electronegativity

A

the ability of an atom to attract a shared pair of electrons in a covalent bond

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5
Q

acid-base character of oxides of period 3 elements

A

Na and Mg oxides are basic
Al oxides amphoteric
Si to Cl oxides are acidic

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6
Q

factors affecting electronegativity

A
  • numbers of shells
  • nuclear charge
  • atomic radius
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7
Q

why is zinc not a transition metal

A

does not have a partially filled d-orbitals, necessary for splitting of transition metals

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8
Q

characteristics of transition metals

A
  • variable oxidation states
  • partially filled d-orbitals
  • catalytic properties
  • form coloured compounds
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9
Q

Ligand

A

species with a lone pair of electrons
binds to a metal ion with a dative bond to form a complex

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10
Q

metabolic bonding

A

The electrostatic attraction between a lattice at positive ions and delocalised electrons

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11
Q

properties of metabolic bonding

A

Malleable–The delocalised electrons allow the layer sat positive ions to slide past each other without disrupting the metallic bonding

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12
Q

ionic bonding

A

the electrostatic attraction between oppositely charged ions in a lattice structure

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13
Q

properties of ionic bonding

A

conductor of electricity in liquid state
non conductor of electricity in solid state - rigged lattice

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14
Q

metalloid elements

A

silicon, germanium, arsenic, antimony, tellurium, polonium – staircase from silicon down

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15
Q

hybridisation

A

mixing of atomic orbitals to form molecular orbitals

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16
Q

sigma and pi bonds formation

A

sigma bonds form through the head on overlapping of orbitals along axial symmetry
pi bonds form through the parallel overlapping of orbitals above and below the line drawn through 2 nuclei

17
Q

calorimetry

A

A technique used to measure the enthalpy associated with a particular change.

assumptions:
- The heat released from the reaction is completely transferred to the water.
- Heat loss to the environment is negligible.
- The maximum temperature reached accurately represents the heat that evolved during the reaction.

18
Q

ionization energy

A

the energy required to move an electron from the ground state to the infinite level.

19
Q

isomerism

A

compounds with same molecular formula but different arrangements of the atoms

20
Q

stereoisomerism

A

different spatial arrangements of atoms in molecules
- configurational: breaking of covalent bonds
- conformational: free rotation about sigma bonds