Combustion Flashcards
Partial pressures
P₁/ P Total = n₁/ n Total = V₁ / nₜ
AFR
= m air / m fuel
Equivalence ratio
= actual AFR / stoichiometric AFR
Dewpoint temperature
T dp is T sat @ PV
Steady reference state
ΔE sys = ΔE state + ΔE chemical
Finding higher heating value for water (liquid from vapour)
HHV = LHV + (N * h fg) H₂O
Lamda sensor
Measures oxygen difference between atmosphere and exhaust -> voltage
4 ways of measuring AFR in lab
Air vs fuel mass flow rate
Lamda sensor
Horiba calculation
Back calculation from exhaust
Flame temperature
Q - W = Σnp (hf° + h - h°) - Σnr (hf° + h - h°)
For aA + bB → cC + dD
write Kp using pressures
Kp = PC ^c * PD ^d / PA ^a * PB ^b
For aA + bB → cC + dD
write Kp using moles
Kp = ( NC ^c * ND ^d / NA ^a * NB ^b )(P/ NT)^Δv
Δv = c + d - a -b
Pollutants from rich combustion
CO CH C
NOx production
Very high temperatures - stoichiometric (slight lean)