Colours of inorganic ions and complexes Flashcards

1
Q

[Cu(H2O)6] 2+

A

pale blue
Cu2+ dissolved in water

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2
Q

[Cu(H2O)4(OH)2] (s)

A

pale blue precip
NH3 dropwise to Cu2+

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3
Q

[Cu(NH3)4(H2O)2] 2+

A

deep/dark blue
excess NH3 to Cu2+

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4
Q

CuCl4 2-

A

yellow
excess HCl to Cu2+

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5
Q

Cu+

A

white precip (CuI)
brown solution (I2)
reduction of Cu2+ with I-

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6
Q

Cu2+/Cu

A

blue sol (CuSO4)
brown solid (Cu)
Cu2+ disproportionation

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7
Q

CoCl4 2-

A

blue
Co2+ (aq) and excess HCl

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8
Q

[Cr(H2O)6] 3+

A

pale purple
(heat –> green)
Cr3+ dissolved in water

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9
Q

Cr(OH)3 (s)

A

dark green precip
NH3 dropwise into Cr3+

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10
Q

[Cr(NH3)6] 3+

A

purple
excess NH3 to Cr3+

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11
Q

[Cr(OH)6] 3-

A

dark green
excess OH- to Cr(OH)3

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12
Q

Cr2O7 2-

A

orange
dissolved and acidified K2Cr2O7 (s)

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13
Q

Cr3+

A

green
oxidised Cr2O7

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14
Q

CrO4 2-

A

yellow
Cr3+ with hot alkaline H2O2

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15
Q

[Mn(H2O)6] 2+

A

pale pink
Mn2+ dissolved in water

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16
Q

Mn(OH)2 (s)

A

pale brown precip
OH- dropwise to Mn2+

17
Q

[Fe(H2O)6] 2+

A

pale green
Fe2+ dissolved in water

18
Q

Fe(OH)2 (s)

A

dark green precip
OH- dropwise to Fe2+

19
Q

[Fe(H2O)6] 3+

A

yellow
Fe3+ dissolved in water