Colours of inorganic ions and complexes Flashcards
[Cu(H2O)6] 2+
pale blue
Cu2+ dissolved in water
[Cu(H2O)4(OH)2] (s)
pale blue precip
NH3 dropwise to Cu2+
[Cu(NH3)4(H2O)2] 2+
deep/dark blue
excess NH3 to Cu2+
CuCl4 2-
yellow
excess HCl to Cu2+
Cu+
white precip (CuI)
brown solution (I2)
reduction of Cu2+ with I-
Cu2+/Cu
blue sol (CuSO4)
brown solid (Cu)
Cu2+ disproportionation
CoCl4 2-
blue
Co2+ (aq) and excess HCl
[Cr(H2O)6] 3+
pale purple
(heat –> green)
Cr3+ dissolved in water
Cr(OH)3 (s)
dark green precip
NH3 dropwise into Cr3+
[Cr(NH3)6] 3+
purple
excess NH3 to Cr3+
[Cr(OH)6] 3-
dark green
excess OH- to Cr(OH)3
Cr2O7 2-
orange
dissolved and acidified K2Cr2O7 (s)
Cr3+
green
oxidised Cr2O7
CrO4 2-
yellow
Cr3+ with hot alkaline H2O2
[Mn(H2O)6] 2+
pale pink
Mn2+ dissolved in water