cobalt chromium Flashcards
What is the function of chromium do in cobalt chromium alloy
- Inert layer of chromium oxide to prevent tarnish
- Solid solution hardening
What are the disadvantages of chromium in cobalt chromium alloy
- Difficult to cast when alloy contains more than 30% chromium
- Hard to solder due to presence of oxide layer on metal surface
How does cobalt affect mechanical properties of cobalt chromium alloy
Increase strength, hardness, modulus of elasticity
What happens as nickel replaces cobalt in cobalt chromium alloy
Less strength, less hardness, lower modulus of elasticity
Lower fusion temperature
Increase in ductility
Function of manganese and silicon in cobalt chromium alloy
Oxide scavengers to prevent oxidation of other elements during melting
Solid solution hardeners
But tend to cause brittleness
Function of boron in cobalt chromium alloy
Deoxidiser, oxide scavenger to prevent oxidation of other elements during melting
Hardener
Reduce ductility. Increase hardness
Function of beryllium in cobalt chromium alloy
Hardener, grain structure refiner, reduce fusion temperature
What does carbon do in cobalt chromium alloy
Formation of carbides, which can precipitate at grain boundaries
How is carbide structure seen in cobalt chromium alloy
Large grains with solid solution matrix showing cored structure with islands of visible interdendritic carbide
Two types of carbide precipitation
Discontinuous and continuous
Effect of carbide on cobalt chromium alloy
Lower ductility. Greater strength. Brittle hence little to no clasp adjustment without fracture [discontinuous carbide precipitation provides greater ductility]
Carbide structures may act as core to increase energy required for fracture but cracks occasionally pass core and result in greater percentage elongation
How to control carbide formation in cobalt chromium alloy to have less decrease in ductility
High fusion temperature and faster cooling of metal more likely to result in discontinuous precipitation
Higher mould temperature will increase carbide spacing, increasing ductility
How does modulus of elasticity of CoCr compare to gold
CoCr modulus of elasticity twice that of gold. Rigid and hard to trim. Less undercut can be used for retentive arm of clasp
Why does cobalt chromium alloy undergo a lot of shrinkage when cooling
2.2-2.5% because high melting temperature of 1250-1500ºC
What are the two types of cobalt chromium alloy
High fusing and low fusing alloy (fusion temperature above and below 1300ºC)
What are the benefits of low fusing alloy
Can be cast into gypsum bonded investment. can be cast against other high fusing precious metal/wrought alloy metals as will not melt other components when molten metal goes into mould space
How to improve ductility of cobalt chromium alloy
Less molybdenum
Less carbon content since carbides make it brittle
Add 5% tantalum
increase melting temperature (discontinuous carbide, increased carbide spacing; but this will result in rougher surface of casting hence better to just accept that cast clasps have low ductility)
What is yield strength
Amount of stress required to cause permanent deformation
How much yield strength should dental alloys have to be used as clasps
4200kg/cm2
How to compensate for casting shrinkage of cobalt chromium alloy
Expansion of investment
Factors affecting casting shrinkage
Surface area to volume ratio. Increased surface area to volume ratio = less casting shrinkage
Strength of investment eg phosphate bonded investment relatively strong