cobalt chromium Flashcards

1
Q

What is the function of chromium do in cobalt chromium alloy

A
  • Inert layer of chromium oxide to prevent tarnish

- Solid solution hardening

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2
Q

What are the disadvantages of chromium in cobalt chromium alloy

A
  • Difficult to cast when alloy contains more than 30% chromium
  • Hard to solder due to presence of oxide layer on metal surface
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3
Q

How does cobalt affect mechanical properties of cobalt chromium alloy

A

Increase strength, hardness, modulus of elasticity

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4
Q

What happens as nickel replaces cobalt in cobalt chromium alloy

A

Less strength, less hardness, lower modulus of elasticity

Lower fusion temperature

Increase in ductility

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5
Q

Function of manganese and silicon in cobalt chromium alloy

A

Oxide scavengers to prevent oxidation of other elements during melting

Solid solution hardeners

But tend to cause brittleness

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6
Q

Function of boron in cobalt chromium alloy

A

Deoxidiser, oxide scavenger to prevent oxidation of other elements during melting

Hardener

Reduce ductility. Increase hardness

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7
Q

Function of beryllium in cobalt chromium alloy

A

Hardener, grain structure refiner, reduce fusion temperature

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8
Q

What does carbon do in cobalt chromium alloy

A

Formation of carbides, which can precipitate at grain boundaries

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9
Q

How is carbide structure seen in cobalt chromium alloy

A

Large grains with solid solution matrix showing cored structure with islands of visible interdendritic carbide

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10
Q

Two types of carbide precipitation

A

Discontinuous and continuous

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11
Q

Effect of carbide on cobalt chromium alloy

A

Lower ductility. Greater strength. Brittle hence little to no clasp adjustment without fracture [discontinuous carbide precipitation provides greater ductility]

Carbide structures may act as core to increase energy required for fracture but cracks occasionally pass core and result in greater percentage elongation

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12
Q

How to control carbide formation in cobalt chromium alloy to have less decrease in ductility

A

High fusion temperature and faster cooling of metal more likely to result in discontinuous precipitation

Higher mould temperature will increase carbide spacing, increasing ductility

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13
Q

How does modulus of elasticity of CoCr compare to gold

A

CoCr modulus of elasticity twice that of gold. Rigid and hard to trim. Less undercut can be used for retentive arm of clasp

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14
Q

Why does cobalt chromium alloy undergo a lot of shrinkage when cooling

A

2.2-2.5% because high melting temperature of 1250-1500ºC

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15
Q

What are the two types of cobalt chromium alloy

A

High fusing and low fusing alloy (fusion temperature above and below 1300ºC)

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16
Q

What are the benefits of low fusing alloy

A

Can be cast into gypsum bonded investment. can be cast against other high fusing precious metal/wrought alloy metals as will not melt other components when molten metal goes into mould space

17
Q

How to improve ductility of cobalt chromium alloy

A

Less molybdenum
Less carbon content since carbides make it brittle
Add 5% tantalum
increase melting temperature (discontinuous carbide, increased carbide spacing; but this will result in rougher surface of casting hence better to just accept that cast clasps have low ductility)

18
Q

What is yield strength

A

Amount of stress required to cause permanent deformation

19
Q

How much yield strength should dental alloys have to be used as clasps

A

4200kg/cm2

20
Q

How to compensate for casting shrinkage of cobalt chromium alloy

A

Expansion of investment

21
Q

Factors affecting casting shrinkage

A

Surface area to volume ratio. Increased surface area to volume ratio = less casting shrinkage

Strength of investment eg phosphate bonded investment relatively strong