Clinical Aspects Of Resin Composite Flashcards
What does composite mean?
Material made of various components that work together
Essential component in resin composite
Filler particles embedded in a matrix made of resin
The 2 are linked together by a silane couponing agent
Composite filler material under EM microscope
Filler takes up a lot of space and resin fills in gaps between filler particles
Early dentals materials made of
Poly methyl methacryalte
(What dentures are made of)
How was poly methyl methacrylate made
Poly methyl methacrylate made from the polymerisation of of methyl methacrylate (small mol)
- imitator and activator (addition polymerisation reaction)
1930’s - developed
1950’s - used for tooth coloured filling materials
What happens in an addition polymerisation reaction?
Monomer mol join together without any loss in material
Polymerisation reaction
- Starts with the production of free radicals
- Free radicals cause double bonds on carbon group and methyl methacrylate to break down leaving an active site which then can cause a chain reaction for other methy methacrylate to join to it
- As this occurs the monomer mol get closer together
- There is a visible and measurable shrinkage within the material because in initial state methyl methacrylate is a liquid so the monomer mol can but around but after polymerisation, they are bound tightly together
Why were early acrylic restoration problematic?
Polymerisation is highly exothermic
Bond to dentine is poor as dentine is wet and acrylic is hydrophobic
Poor bond to tooth so easily pulled away from dentine causing gaps
Which leads to;
Poor retention, Staining, Sensitivity, Secondary caries
How did they combat shrinkage?
If larger mol of methyl methacrylate is used, there is less shrinkage
Because larger mol already occupy a lot of space per molecule so fewer polymerisation reaction to occur within the same vol of material
What is the main resin used in composite now?
Bis-GMA
- thick
- viscous
What other polymers take part in the polymerisation reaction?
Diligent monomers (smaller) - TEGDMA
- help Bis-GMA be more flowable
Why was the addition of a filler important for composite?
Eg silica
- take up space so fewer polymerisation reactions occur therefore, less shrinkage
use of filler particles
Play no part in the setting reaction
• Take up the space of the resin – so less resin – less shrinkage
• Add advantageous properties to the material
• Increase wear resistance
• Strength
• Radio-opacity
• Allows different colour composite
What size filler particles are preferable and why?
The larger the particle the higher the strength at the expense of aesthetics
• Small particles make for a weaker material, give better polishability but hard to add a very large amount so more shrinkage
• Most composites contain a mixture of different size filler – a “hybrid” – more space can be taken up if smaller particles are added with larger particles
Typical components of modern composite
Bis-GMA - Main polymerisable monomer
TEGDMA - Diluent monomer
Camphorquinone (CQ) - Initiator (Forms free radicals but requires presence of DMAEMA)
Silica filler -
- strength
- wear resistant
- colour
- radiopacity
Silane coupling agent - Binds filler to matrix
Effect of fillers on properties
More filler + larger monomers =
More filler + larger monomers =
Advantages
- Improved mechanical properties
- Less shrinkage
Disadvantages
- Reduced curing depth
- Reduced flowability
Properties of composite
Advantages
- strong
- hard wearing
- easy to place
- easy to polish
- good aesthetics
- less destructive prep than amalgam, crowns or veneers
Properties of composite
Disadvantages
- hydrophobic (have to create a dry area to use composite)
- polymerisation shrinkage
- time consuming (rubber dam etc)
- does not bond to tooth requires a separate bonding agent