CIP 1 Day 1 and 2 Flashcards
The deterioration of a material, usually a metal, that results from a reaction with its environment
Corrosion
The formation of a thin surface layer of corrosion product can form an effective barrier against further attack that can slow down the rate of corrosion process.
Passivation
For corrosion to occur; certain conditions and elements are essential.
Corrosion Cell
The electrode of an electrochemical cell at which oxidation occurs. Electrons flow away from the anode in the external circuit. Corrosion usually occurs and metal ions enter the solution at the anode.
Anode
The electrode of an electrochemical cell at which reduction is the principal reaction Electrons flow towards the cathode in the external circuit.
Cathode
Connects the anode and the cathode and allows passage of electrons, generated at the anode, to the cathode.
Return Path
Medium that conducts ionic (rather than electronic) current
Electrolyte
The oxide layer formed during hot fabrication or heat treatment of metals. A blue-black layer of iron/iron-oxide; cathodic relative to substrate; Generally removed prior to painting
Mill Scale
A list of materials in order of their corrosion potentials; with the most easily corroded, or most active, at the top and the least active at the bottom.
Galvanic Series
Relatively uniform loss of material over the entire surface and in general thinning of the affected surface.
Generalized Corrosion
Occurs at discrete sites on the metal surfaces. Usually at defects in coating; Changes in contaminants or pollutants, changes in the electrolyte.
Localized Corrosion
Corrosion does not proceed uniformly but primarily occurs at distinct spots where deep pits are formed.
Pitting Corrosion
Occurs on a metal surface that is shielded from full exposure to the environment because of the close proximity of another material that forms a narrow gap between them.
Crevice Corrosion
Substance that, when added to an environment, prevents or decreases the rate of corrosion.
Corrosion Inhibitor
A technique to reduce the corrosion of a metal surface by making the surface the cathode of an electrochemical cell. Uses sacrificial anodes, magnesium, zinc or aluminum, that will corrode in preference to the steel structure they are connected to.
Cathodic Protection
A reduction of the anodic reaction rate of an electrode involved in corrosion
Passivation
What are the elements of a corrosion cell?
Anode, cathode, metallic path and electrolyte
Different concentrations of oxygen on the same metal usually occurs in immersion conditions.
Oxygen Concentration Cell
Increase the rate of corrosion by increasing the efficiency (conductivity) of the electrolyte.
Chemical Salts
Causes very rapid rusting; Airborne salts and chemical pollutants. Humidity and seawater provide the electrolyte.
Chemical/Marine Environment
Highly corrosive environment because of the gases, chemicals and high humidity
Chemical with High Humidity
Gases and chemicals stimulate corrosion even in low humidity
Chemical with Low Humidity
Provides an active electrolyte because of the moisture and the salt particles
Marine with High Humidity
Chemical with High Humidity
Highly corrosive environment because of the gases, chemicals and high humidity
Marine with High Humidity
Provides an active electrolyte because of the moisture and the salt particles
Chemical with Low Humidity
Gases and chemicals stimulate corrosion even in low humidity.
Splash Zone Area
Mid-tide to 12 ft above high tide
Rural Environments
Least corrosive environment due to clean air, few pollutants and low moisture
Least corrosive environment due to clean air, few pollutants and low moisture.
Rural Environments
What occurs at the anode?
Metal ions enter into the solution and corrosion usually occurs at this location, generates the electrons
What is the function of the electrolyte?
To carry the metal ions to the cathode and to complete the electrical path
What is the function of the metallic path?
To carry the electrons connecting the anode and the cathode
5 Factors that affect the rate of corrosion
Oxygen, temperature, chemical salts, humidity and pollutants and acid gases.
Common tools to control corrosion?
Design, inhibitors, material selection, cathodic protection, protective coatings, splash zone systems, alteration of environment.
Mission statement: Undertake simple coating ________ under _________.
Inspection work; direct supervision of a qualified level III inspector
Mission statement: Read and comprehend a _________ ___________.
Coating specification for surface preparation and coating application