Chp -2 Acid Bases And Salts Flashcards
what are acids and what are some physical characteristic propertires of it?
The word acid has been derived from the latin word 'acidus" meaning sour to taste. . Acid is the substance which when dissolved in water, ionizes and releases hydrogen ions or hydronium ions (H3O) in the soln . HCL(aq)---> H+ + Cl- HCL+ H2O---> H3O+ + Cl- properties of acids- - taste sour corrosive on ksin -good conductor of electricity -exothermic when diluted
write a note on litmus and name other natural indicators
litmus soln is a purple dyet, which is extracted from lichen, a plant belonging to the division thallophyta and i s commonly used as an indicator. When the litmus
solution is neither acidic nor basic, its colour is purple. There are many other natural
materials like red cabbage leaves, turmeric, coloured petals of some flowers such as
Hydrangea, Petunia and Geranium, which indicate the presence of acid or base in a
solution. These are called acid-base indicators or sometimes simply indicators.
what are indicators and olfactory indicators? give exampls
An indicator is an dye that changes colour when it is put into an acid and a base. Olfactory indicators are those indicators that help to identify whether the given solution is acidic or basic by changing their smell instead of colour as other indicators do. For example onion, vanilla extract, clove, etc
Onion: Paste or juice of onion loses its smell when added with base. It does not change its smell with acid.
vanilla: smell of vanilla vanishes with base.
what are the effects acids and bases have on indicators
ACIDS- -blue litmus red - methyl orange-red -phenolphthalein- colourlesss in acids turmeric paper- no change BASES- -red litmus blue -methyl orange yellow - phenolphthalein- pink -turmeric paper reddish brown
explain how acids react with metals, how base react with metals
Acids + metal → salt+ h2
Fe+ H2SO4 →FeSO4 + H2
Bases + metals - Metals like zinc tin and aluminium react with strong alkali like caustic soda and Caustic potash to evolve hydrogen gas -2NaOH(aq) +Zn (s)→ Na2ZnO2(S)+ H2 - 2 Al + 2NaOH —-> Na2ZnO2+ H2 -Sn + 2NaOH —-> Na2SnO2 + H2
dry HCL is not acidic. why?
The acidic behaviour of acids is due to the presence off hyydrogen ions. The acids produce hydrogen ions only in the presence of water.(H3O). So, in the basence of water, a substance will not form hydrogen ion and hence HCL wont show the acidic property. Y
classify acids on the basis of sources
1)minerals acids- obtained from rocks and minerals. All mineral acids are strong except carbonic acid(used in fizzy soft drinks n soda water)
for exampls- HCL,H2SO4, HNO3, H2CO3, H3PO4
2)Organic acids-obtained ffrom plant and animals .
for eg- formic acid, acetic acid ,benzoic acid, citric acid.
what is basicity?
Basicity of an acid is determined by no. of hydronium ion /h+ produced per molecule of an acid on complete ionisation.
classify acids on the basis of their basicitry
1) monobasic acids- on emolecule of acid gives one hydronium ion.Cfor eg- HCL,Hbr,etc.
2) dibasic acids- one molecule of acid gives two hydronium ion. H2SO4, H2CO3
3) Tribasic acid- one molecule of acid gives 3 hydronium ion.H3PO4, citric acid (C6H8O7)
Classify acids on the basis of their strength
Strong acids: they undergo complete ionisation in aqueous solutions.
Strong acids also have a high electrical conductivity because of the high concentration of hydrogen ions in their solution. Thus, all the strong acids are strong electrolytes.
For example: HCL,H2SO4.
Weak acids : they undergo incomplet ionisation in aqueous solution.
• Due to a small amount of hydrogen ions present in their solutions, weak acids react quite slowly with other substances (such as metals, metal carbonates and metal hydrogencarbonates, etc.).
•Weak acids have low electrical conductivity because of the low concentration of hydrogen ions in them
For example_ CH3COOH(acetic acid) HCOOH, H2CO3(carbonic acid) H2SO3(sulphurous acid)
classify acids on the basis of concentration
concentrated- they have less amount of water and more amount of acid.
Dilute- they have more water and less acid.
what are bases and alkalis? give some physical prop.
according to arrhenius theory” Those substances which give hydroxide or hydroxyl ion in their aqueous solutions are called bases”.
NaOH(aq) → Na+(aq) + OH-
•All metal oxides and metal hydroxides are bases.
•metal carbonates and metal hydrogencarbonates are also considered to be bases because they neutralise the acids hus, sodium carbonate (Na2CO3)calcium carbonate (CaCO3,) and sodium hydrogen carbonate (NaHCO3) are also bases.
•bases which are completely dissolvable in water are called alkalis.for eg-NaOH,KOH.
properties-
-bitter to taste
-soapy texture
-good conductors of electricity
-release heat when diluted
Uses of bases
Sodium hydroxide is used in the manufacture of soap, paper and a synthetic fibre called ‘rayon’.
- Calcium hydroxide (called slaked lime) is used in the manufacture of bleaching powder.
- Magnesium hydroxide is used as an ‘antacid’ to neutralise excess acid in the stomach and cure indigestion.
- Sodium carbonate is used as washing soda and for softening hard
- Sodium hydrogencarbonate is used as baking soda in cooking food, for making baking powders, as an antacid to cure indigestion Ammonia solution and in soda-acid fire extinguishers.
Is acid is present on other planets
The atmosphere of planet Venus is made up of thick white and yellowish Clouds of sulphuric acid. So life cannot exist on the planet Venus
What is the acidity of a base
acidity of a base is determined by the no. of hydroxyl_OH-) Ion produced per molecules of a base or alkali on complete dissociation in water.
t/f 1)The strength of an acid depends on concentration of acid And on dilution strength of acid or base
increases
2s long as baking powder is dry, the sodium hydrogencarbonate and tartaric acid present in
it do not react with each other.
3)baking soda and baking powder are single compounds
1)F: depends on the concentration of hydronium ion And on Dilution strength of acid or base decreases.
2) T
3)FALSE:Baking soda is a single compound : sodium hydrogencarbonate. On the other hand, baking powder is a mixture of sodium hydrogencarbonate and a
solid, edible acid such as tartaric acid (or citric acid)
Classify bases on the basis of acidity-
Mono acidic bases-= produce 1 hydroxyl ion per molecule. NaOH, KOH,.
Diacidic- produce 2 hydroxyl ion per molecule
CaOH)2, Ba(OH)2, Mg(OH)2
tri- acidic- produces 3 hydroxyl ion per base molecule. Al(OH)3, Fe(oh)3
Classify bases on the basis of strength
1) strong bases- undergo completer ionisation in aqueous soon. Do eg- NaOH,KOH, CaOh)2
2) weak bases- Undergo incomplete ionisation in aq soln. For eg- NH4OH, Al(OH)3,etc
Classify bases on the basis of concentration
Concentrated- contain less amount of water and more amount of base
Dilute- large amount of water and less amount of baseboard
What is caustic potash and caustic potash and soda ash
Bases like NaOH and KOH have corrosive nature that is they are caustic, so are known as caustic soda b caustic potash.
anyhydrous sodium crabonate is genrally called soda ash( one the source is ashes of plants)
While diluting an acid, why is it recommended that the acid should be added to water and not water to the acid?
When a concentrated acid is added to water for preparing a dilute acid, then the heat is evolved gradually and easily absorbed by the large amount of water (to which the acid is being added) however if water is added to concentrated acid, then large amount of heat is evolved at once. This heat changes some of the water to steam explosively which can splash the acid on our face or clothes and cause acid burns. Even the glass container may break due to the excessive heating.
What happens on passing excess CO2 through the solution of calcium carbonate
CaCO3 +H2O +CO2 —-> Ca(HCO3)2
Define neutralisation and endpoint
Neutralisation maybe defined as the reaction between acid and base present in aqua solution to form salt and water. Neutralisation is the combination of hydrogen ion of an acid and hydroxyl ion of a base to form water
The complete neutralisation of an acid solution by a base and vice versa is indicated by sudden change in the colour of the indicator present. This is called endpoint. It implies that H+ irons of the acid have completely reacted with hydroxyl irons of the base to form water which is neutral