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Physics Formulas > Chemistry Reactions > Flashcards

Chemistry Reactions Flashcards

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1
Q

Finkelstein Reaction

A

Reaction of alkyl chloride or bromide with sodium iodide (or methanol) in the presence of acetone to give alkyl iodide

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2
Q

Swartz Reaction

A

Reaction of alkyl chloride or bromide with metal fluorides to give alkyl fluoride

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3
Q

Wurtz Reaction

A

Reaction of two same/different alkyl halides in the presence of sodium and dry ether to produce an alkane and sodium halide

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4
Q

Wurtz-Fittig Reaction

A

Reaction of an alkyl halide with an aryl halide(with the same halogen group) in the presence of sodium and dry ether to give a substituted aromatic compound and sodium halide

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5
Q

Reaction of alcohol with hydrogen bromide

A

Alcohol reacts with hydrogen bromide (48% boiling) in the presence of sodium bromide and sulfuric acid (on heating) to produce an alkyl bromide and water

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6
Q

Reaction of alcohol with hydrogen iodide

A

Alcohol reacts with hydrogen iodide in the presence of sodium iodide and h3po4 to give alkyl iodide and water

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7
Q

Reaction of alcohol with phosphorous trihalide

A

alkyl halide and h3po4

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8
Q

Reaction of alcohol with phosphorous pentachloride

A

alkyl chloride, pocl3, hcl

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9
Q

Reaction of alcohol with thionyl chloride

A

alkyl chloride, so2(gas), hcl(gas)

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10
Q

Reaction of toulene and bromine in the presence of dark Fe

A

ortho and para substituted bromotoulene

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11
Q

Dows Process

A
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12
Q

1) Reaction of alkenes with sulfuric acid
2) reaction of alkenes with diborane

A
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13
Q

Reaction of carboxylic acid with alcohol

A
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14
Q

Preparation of phenol with isopropyl benzene

A
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15
Q

Preparation of phenol using benzene sulfonic acid

A
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16
Q

Preparation of benzene using aniline

A
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17
Q

Reaction of alcohol with a simple ester

A

mixed ester and carboxylic acid

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18
Q

Reaction of alcohol with acid chloride

A

ester and hcl

19
Q

Reaction of primary, secondary and tertiary alcohols with Cu at 573K

A
20
Q

Reaction of phenol with bromine in the presence of
1)h2o
2)carbon disulfide

A
21
Q

Reaction of phenol with hno3 in the presence of
1) nothing
2) conc. h2so4

A
22
Q

Reaction of phenol with sulfuric acid at
1) room temperature
2)373K

A
23
Q

Riemer Tiemann Reaction

A

salicylaldehyde

24
Q

Kolbe Reaction

A

salicylic acid

25
Q

Reaction of alcohol with sulfuric acid at
1)413K
2)443K

A

1)ether
2)alkene

26
Q

Williamson synthesis

A
27
Q

Reaction of ether with
1) dilute h2so4
2)pcl5
3)hi or hbr
4) long contact with oxygen

A
28
Q

Make the structures of the following
1) hydroquinone
2)alpha naphthol
3)resorcinol
4)catechol
5)para-cresol
6)pyrogallol
7)phloroglucinol

A
29
Q

Preparation of aniline using nitrobenzene

A
30
Q

Ammonolysis

A
31
Q

What happens when Ammonolysis is performed in the presence of excess
1)alkyl halide
2)excess ammonia

A
32
Q

Preparation of amines using nitriles and amides

A
33
Q

***Gabriel phthalimide Synthesis

A
34
Q

***Hoffman Bromamide synthesis

A
35
Q

Is alkanamine a stronger base than ammonia

A

Yes

36
Q

Is aniline a stronger base than other aryl amines and ammonia

A

No

37
Q

Acylation

A

Amide and HCL
Tertiary amines do not show acylation reactions

38
Q

Carbylamines Reaction

A

Formation of alkyl isocyanide, potassium chloride and water
Only primary amines give the carbylamines test

39
Q

Reaction of primary, secondary, tertiary and aryl amines with nitrous acid

A

primary: diazonium salts
secondary amines: n-nitroso amines
tertiary: nitrate salts
aryl: diazonium salts

40
Q

Hinsberg Reagent Test

A

Primary amines form sulfonamides soluble in an alkali
secondary amines form a sulfonamide insoluble in an alkali
tertiary amines do not react with the Hinsberg reagent

41
Q

Reaction of aniline with hno3 in the presence of h2so4

A

51% para product
47% meta product
2% ortho product

42
Q

Sandmeyer Reaction for amines

A
43
Q
A

Physics Formulas (3 decks)

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