Chemistry parcial II Flashcards

1
Q

Acid dehydration of alcohol

A

Reactant: Alcohol

Catalyst: H2SO4 & 180º

Product: Alkene + H2O

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2
Q

Etherification of Alcohol

A

Reactant: 2 identical alcohols

Catalyst: H2SO4 & 140º

Product: Ether + H2O

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3
Q

Oxidation of Alcohol (primary)

A

Reactant: Primary alcohol + (O)

Catalyst: OX. & -2H

Product: Aldehyde + H2O

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4
Q

Oxidation of Alcohol (secondary)

A

Reactant: Secondary alcohol + (O)

Catalyst: OX. & -2H

Product: Ketone + H2O

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5
Q

Oxidation of Alcohol (tertiary)

A

Reactant: Tertiary alcohol + (O)

Catalyst: OX. & -2H

Product: NO REACTION

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6
Q

Aldehyde Oxidation

A

Reactant: Aldehyde

Catalyst: OX./+O

Product: Carboxylic Acid

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7
Q

Aldehyde Hydrogenation

A

Reactant: Aldehyde + H2

Catalyst: Pt

Product: Primary Alcohol

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8
Q

Ketone Oxidation

A

NO REACTION

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9
Q

Ketone Hydrogenation

A

Reactant: Ketone + H2

Catalyst: Pt

Product: Secondary Alcohol

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10
Q

Carboxylic Acid Reduction

A

Reactant: Carboxylic Acid

Catalyst: Red. & -O

Product: Aldehyde

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11
Q

Carboxylic Acid Amidation

A

Reactant: Carboxylic Acid + Amine

Catalyst: Heat

Product: amide + H2O

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12
Q

Carboxylic acid Esterification

A

Reactant: Carboxylic Acid + Alcohol

Catalyst: H+, Heat

Product: Ester + H2O

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13
Q

Ester Hydrolisis

A

Reactant: Ester + H2O

Catalyst: H+, heat

Product: Carboxylic Acid + Alcohol

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14
Q

Functions of Carbohydrates

A

Store Energy
Protect
Supply Carbon
Structural Elements

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15
Q

Basic unit of carbohydrates

A

Monosaccharides (simple sugars)

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16
Q

2 monosaccharides bonded

A

Disaccharides

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17
Q

Many saccharides bonded

A

Polysaccharides

18
Q

Properties of saccharides

A

Are Aldehydes or Ketones with OH

Extremely Soluble

Sweet

Solid

19
Q

3 Most important monosaccharides

A

Glucose
Galactose
Fructose

20
Q

Maltose

A

Glucose + Glucose

21
Q

Lactose

A

Glucose + Galactose

22
Q

Surcose

A

Glucose + Fructose

23
Q

Name of bonding between saccharides

A

Glycosidic linkage

24
Q

Starch

A

Amylose and amylopectin
Found in potatoes
Store glucose

25
Glycogen
Densely branched glucose units | Store glucose in animals
26
Cellulose
10,000 glucose units Indigestible Structural functions in plants
27
Functions of lipids
Store energy Protective wax coating Insulate Structural Components
28
Fatty acid definition
Building blocks of saponifiable lipids Carboxylic acid chains with 2 parts Permit transport of lipids through blood and to cells
29
Types of fatty acid
Saturated: only single bonds, solid, unhealthy Monosaturated: Only one double bond, liquid, healthy Polyunsaturated: Several double bonds, liquid, healthy af
30
Triglyceride
``` Saponifiable lipids store energy provide insulation found in oil triple esters of glycerol ```
31
Wax
Saponifiable complex Protective coating Esters of alcohol and one fatty acid
32
Phospholyceride
Saponifiable complex Protect cells Esters of alcohols, 2 fatty acids, phosphate aminoacid
33
Steroid
Non saponiifable 4 rings Bile Cholesterol in cell membranes
34
2 Types of triglycerides
Fats: Made of saturated fatty acids Oils: Made of unsatured fatty acids
35
Saponification
A reaction of salts in fatty acids which produces soap
36
Functions of proteins
``` Catalytic Structural Storage Protection Regulation Transport Movement Nerve transmission ```
37
Chemical bond between 2 aminoacids
Peptide bond | More than 50 aminoacids form a protein
38
Primary protein structure
Linear sequence of aminoacids in a protein chain held by peptide bonds
39
Secondary protein structure
Arrangement of a protein chain in one of 2 patterns (alpha helix or beta pleated) held in place between hydrogen bonds
40
Tertiary protein structure
Tridimensional shape of a protein caused by cross links between chains
41
Quaternary protein structure
Arrangement of polypeptide sub units to form a larger protein