Chemistry of the Atmosphere Flashcards
What are the proportions of gases in the air?
80% Nitrogen
20% Oxygen
small proportion of other gases: Carbon dioxide, water vapour, noble gases
Why is evidence for the early atmosphere and its formation limited?
Due to the time scale of 4.6 billions years
What is a theory of the formation of the early atmosphere?
During first billion years of Earth’s existence
- intense volcanic activity, released gases forming the early atmosphere
- released water vapour-> condensing into oceans
- volcanoes produced nitrogen: gradually built up in atmosphere, also small proportions of methane and ammonia
What was the Earth’s atmosphere like during the beginning of the period of the atmosphere forming?
Earth’s atmosphere similar to current Mars or Venus atmosphere (mainly CO2, little oxygen)
During the formation of the atmosphere, what happened when oceans formed?
- Carbon dioxide dissolved into the water
- ## Carbonates precipitated-> produced sediments, reducing amount of CO2 in atmosphere
What is the photosynthesis equation?
6CO2 + 6H2O -> C6H12O6 + 6O2
produced by algea and plants during the formation of the early atmosphere-> increasing oxygen, decreasing carbon dioxide
How did the percentage of oxygen in the atmosphere gradually increase?
- first produced oxygen around 2.7 billion years ago-> began appearing in atmosphere
- over next billion years: plants evolved, % of oxygen increased
- eventually enabled animals to evolve
How did levels of Carbon dioxide decrease in the early atmosphere?
- algea and plants due to photosynthesis
- formation of sedimentary rocks and fossil fuels that contain carbon
- dissolved into oceans-> reacted to form carbon precipitates that formed sediments on the seabed
What are Greenhouse Gases and what do they do?
Maintain temperatures in the atmosphere on Earth to support life
- Water vapour, Carbon dioxide, Methane
How are fossil fuels formed?
Crude oil and natural gas- deposits of plankton, form thick reservoirs under the seabed
Coal- sedimentary rock made from thick plant deposits
Limestone- sedimentary rock, calcium carbonate deposits from shells and skeletons of marine organisms
How does plants, plankton and marine animals dying lock carbon away?
- the organisms die and sink to the seabed
- then get buried under layers of sediment
- become compressed and form sedimentary rocks, oil and gas over millions of years
- trapping carbon within- reducing CO2 levels in the atmosphere
What is the evidence from volcanoes for the evolution of the early atmosphere?
- Gases released by volcanoes today are similar to volcanoes that erupted billions of years ago
- gives evidence as to what gases were present in the early atmosphere
What is the evidence from other planets for the evolution of the early atmosphere?
- Atmosphere of planets where there is no life (Mars, Venus etc)
- Can be used to predict what atmosphere might have been like before life evolved.
What is the evidence from rocks for the evolution of the early atmosphere?
- Certain rocks called ‘Red beds’ contain lots of iron oxide.
- Can only form when there is enough oxygen in the atmosphere to react with iron
- Age of red beds can be used to predict at which point oxygen levels reached a particular level in the atmosphere.
What is the evidence from living things for the evolution of the early atmosphere?
- Some simple organisms (ie early bacteria), DONT rely on reactions involving oxygen to release energy
- Use other gases (ie carbon dioxide)
- Fossils of bacteria have been found which are older than fossils of creatures that depend on oxygen
- Implies life first evolved without need for oxygen, so not much in the early atmosphere