Chemistry Module 3.1 Flashcards
In the early 1800s, what were the only ways to categorise elements?
In the early 1800s, the only two ways to categorise elements were by their physical and chemical properties and their relative atomic mass. This was due tot he fact at this time, they only knew how to measure the relative atomic mass.
In 1817, who attempted to group similar elements?
johann Dobereiner attempted to group similar elements - these groups were called Dobereiner’s triads. He saw that chlorine, bromine and iodine had similar characteristics. He also realised that the other properties of bromine (e.g. atomic weight) fell halfway between those of chlorine and iodine. He found other groups of three elements (e.g. lithium, sodium and potassium), and called the triads. It was a start.
In 1863, who made another table of elements?
An English chemist called John Newlands had the first good attempt at making a table of elements in 1863. He noticed that if he arranged the elements in order of mass , similar elements appeared at regular intervals - every eighth element was similar. He called this the law of octaves, and he listed some known elements in rows of seven so that the similar element s lined up as columns.
What was the issue with John Newlands table of elements?
The law of octaves broke down in the third row, with many transition metals like Fe, Cu and Zn disrupting the pattern.
Who created the first accepted version of the periodic table?
Russian chemist, Dmitri Mendeleev produced a better table, which isn’t far off from the one we have today. He arranged all the known elements by atomic mass, but left gaps in the table where the next element didn’t seem to fit. That way he could keep elements with similar chemical properties in the same group. He also predicted the properties of undiscovered elements that would go in the gaps correctly.
How is the periodic table arranged?
The periodic table is arranged into periods (rows) and groups (columns).
What do all the elements within a period have the same number of?
All the elements within a period have the same number of electron shells.
Define periodicty.
Periodicity is the repeating trends in the physical and chemical properties of the elements across each period.
What do all the elements within a group have the same number of?
All the elements within a group have the same number of electrons in their outer shell. This means they have similar chemical properties.
Split the periodic table into an s block, d block and p block.
{Correctly split periodic table}
Define what is means for an atom to be ionised.
When electrons from an atom have been removed it has been ionised.
What is meant by the first ionisation energy?
The first ionisation energy is the energy needed to remove 1 mole of electrons from 1 mole of gaseous atoms.
Why is ionisation an endothermic reaction?
Ionisation is an endothermic reaction because you have to put energy in to a molecule to ionise it.
What is the equation for the 1st ionisation energy of an oxygen atom?
O (g) → O⁺ (g) + e⁻
What are the three most important points about ionisation energies?
- You must always use state symbols, (g), because ionisation energies are measured for gaseous atoms.2. Always refer to 1 mole of atoms, as stated in the definition, rather than to a single atom.3. The lower the ionisation energy, the easier it is to form an ion.
How does Nuclear charge affect ionisation energy?
The more protons there are in the nucleus, the more positively charged the nucleus is and the stronger the attraction for the electrons.
How does Atomic radius affect ionisation energy?
Attraction falls off very rapidly with distance. An electron close to the nucleus will be much more strongly attracted than one further away.
How does shielding affect ionisation energy?
As the number of electrons between the outer electrons and the nucleus increases, the outer electrons feel less attraction towards the nuclear charge. This lessening of the pull of the nucleus by inner shells of electrons is called shielding.
What does a high ionisation energy mean in an atom?
A high ionisation energy means there’s a strong attraction between the electron and the nucleus, so more energy is needed to overcome the attraction and remove the electron.
What happens to ionisation energies as you go down the group?
As you go down a group in the periodic table, ionisation energies generally fall, i.e. it gets easier to remove outer electrons.
Why do the ionisation energies fall as you go down the group?
feeIonisation energies go down a group because: Elements further down a group have extra electron shells compared to ones above. The extra shells mean that the atomic radius is larger, so the outer electrons are further away from the nucleus, which greatly reduces their attraction to the nucleus.The extra inner shells shield the outer electrons from the attraction of the nucleus.This provides evidence that electron shells really exist - a decrease in ionisation energy going down a group supports the Bohr model of the atom.
What is the general trend for the ionisation energies as you move across a period and why?
As you move across a period, the general trend is for the ionisation energies to increase - more energy is required to remove the outer electrons.This is because the no. of protons is increasing. As the positive charge of the nucleus increases, the electrons are pulled closer to the nucleus, making the atomic radius smaller.The extra electrons that the elements gain across a period are added to the outer energy level so they don’t really provide any extra shielding effect (shielding works with inner shells mainly).
What are the two exceptions to the general trend of ionisation energies increasing across a period?
There are two exceptions to the trend:The first ionisation energy decreases between groups 2 and 3, and between groups 5 and 6.
Why is there a drop in ionisation energy between groups 2 and 3?
- The outer electron in group 3 elements is in a p orbital rather than an s orbital.2. A p orbital has a slightly higher energy than an s orbital in the same shell, so the electron is, on average, to be found further from the nucleus.3. The p orbital also has additional shielding provided by the s electrons.4. These factors override the effect of the increased nuclear charge, resulting in the ionisation energy dropping slightly.