Chemistry GCSE: C4 Chemical Changes Flashcards
What pHs do alkalis have?
Which pH is the most alkali?
Alkalis have pHs above (greater than) 7
pH 14 is the most alkali
What pHs do acids have?
Which pH is the most acidic?
Acids have pHs below 7
pH 0 is the most acidic
What pH is neutral?
pH7
Give two ways that you can measure the pH of a substance.
Say which is better and why?
Universal indicator or a pH probe
A probe gives a more precise (and accurate) reading.
What colour does universal indicator go in
Strong acids
Weak acids
Strong acids: Red
Weak acids: Orange/yellow
What colour does universal indicator go in
Strong alkalis
Weak alkalis
Strong alkalis: Purple
Weak alkalis: Blue
What colour does universal indicator go in
Neutral solutions
Neutral solutions: Green
What type of ions do alkalis contain
Hydroxide ions (OH-)
What type of ions do acids contain
Hydrogen ions (H+)
What is the difference between alkalis and bases?
A base: any substance that reacts with acids to form a salt (all alkalis are bases)
Alkalis: Bases that dissolve in water
Some bases e.g iron oxide are not alkalis as they don’t dissolve in water.
What do we call reactions between acids and alkalis/bases?
Neutralisation reactions
Why does adding acids and alkalis/bases together lead to neutralisation?
Because the hydrogen ions react with the hydroxide ions to make water.
H+ + OH- => H2O
Metal oxides (e.g magnesium oxide) are bases. What two other types of compunds are bases?
Metal hydroxides (e.g sodium hydroxide) and metal carbonates (e.g calcium carbonate).
What two things are made when metals react with acids?
Complete this reaction: Sulfuric acid + magnesium =>
A salt and hydrogen
Sulfuric acid + magnesium => magnesium sulfate + hydrogen
What two things are made when metal oxides or metal hydroxides react with acids?
Complete this reaction: Hydrochloric acid + iron oxide =>
A salt and water
Hydrochloric acid + iron oxide => iron chloride (a salt) + water
What three things are made when metal carbonates react with acids?
Complete this reaction: Nitric acid + calcium carbonate =>
A salt, water and carbon dioxide
Nitric acid + calcium carbonate => calcium nitrate + water + carbon dioxide
What types of salts are made using hydrochloric acid?
Chlorides (e.g calcium chloride)
What types of salts are made using nitric acid?
Nitrates (e.g copper nitrate)
What types of salts are made using sulfuric acid?
Sulfates (e.g iron sulfate)
List the steps to make a soluble salt (e.g copper sulfate) from an insoluble base (e.g copper oxide) and an acid (e.g sulfuric acid)
- Gently warm the acid in a water bath
- Add the insoluble base to the acid until no more reacts (it is in excess)
- Filter to remove any insoluble base
- Heat the solution to evaporate the water
- Filter and/or dry the crystals made
Put these metals in order or their reactivity: Potassium, magnesium, lithium, calcium, sodium.
Explain how you worked this out
Click here for the periodic table
Potassium, sodium, lithium, calcium, magnesium.
Group 1 elements first (from bottom to top).
Group 2 elements next (from bottom to top)
Put the following in order of reactivity:
- Acid reactions
- Iron
- Carbon
- Zinc
- Copper
- Carbon (most reactive)
- Zinc
- Iron
- Hydrogen
- Copper (least reactive)
Cheeky Zebras Irritate Happy Crocodiles
What two things are made when metals react with water?
Complete the following equation: Magnesium + water =>
Metal hydroxides and hydrogen
Magnesium + water => Magnesium hydroxide and hydrogen
Which metals don’t react with water?
Zinc and metals that are less reactive than zinc (e.g iron, copper, silver)
Name two metals that are found as pure metals.
Why are these metals found as pure metals?
Gold and silver
Because they are very unreactive.
Most metals are not found as pure metals, they are found as metal ores. What type of compounds are metal ores.
Metal ores are metal oxides.
What two methods can be used to extract metals such as iron from their metal ores/oxides?
Displacement using carbon
Electrolysis
Why can carbon be used to extract zinc, iron and copper from their ores/oxides?
Because carbon is more reactive than zinc, iron, copper and so will displace them from their oxides.
Why can’t carbon be used to extract aluminium from its ore/oxide?
Because carbon is less reactive than aluminium.
Why are zinc, iron and copper extracted using carbon (displacement) instead of using electrolysis?
Electrlysis is much more expensive because….
Melting metal ores uses lots of energy
Creating an electric current uses lots of energy
Describe oxidation and reduction in terms of oxygen.
Oxidation is gain of oxygen
Reduction is loss of oxygen
In the following reaction, what has been oxidised and what has been reduced?
zinc oxide + carbon → carbon dioxide and zinc
The carbon is oxidised (gains oxygen)
The zinc oxide is reduced (loses oxygen)
HIGHER:
Describe oxidation and reduction in terms of electrons (OIL RIG)
- *O**xidation is loss of electrons
- *R**eduction is gain of electrons
In electrolysis, what is the charge of the anode and what is the charge of the cathode?
PANIC
Positive Anode
Cathode Is Negtive
Whay does electrlysis mean?
What is it used for?
Using electricity (electro) to break things up (lysis).
Breaking up ionic compunds into their elements.
In what state do ionic compounds have to be for electrolysis.
Liquid/molten
or
Aqueous/dissolved/in a solution
What does aqueous mean
It means that the substance is dissolved in water/in a solution.
What charge do non-metal ions have?
In electrolysis, which electrode do the non-metal ions go to?
Non-metal ions have a negative charge
They are therefore attracted to the anode (positive electrode)
What charge do metal ions have?
In electrolysis, which electrode do the metal ions go to?
Metal ions have a positive charge.
So they are attracted to the cathode (negative electrode)
In electrolysis, what happen to negative ions when they arrive at the anode (positive electrode)?
They lose electrons (oxidised) forming molecules (or atoms).
In electrolysis, what happen to positive ions when they arrive at the cathode (negative electrode)?
They gain electrons (reduced) forming metal atoms
What happens at the anode (positive electrode) during electrolysis of molten aluminium oxide?
- Negative oxide ions
- Lose electrons (oxidised)
- Forming oxygen molecules
- 2O2- → O2 + 2e-
What happens at the cathode (negative electrode) during electrolysis of molten aluminium oxide?
- Positive aluminium ions
- Gain electrons electrons (reduced)
- Forming aluminium atoms
- Al3+ + 3e- → Al
HIGHER: What happens at the anode (positive electrode) during electrolysis of aqueous copper chloride?
- Negative chloride ions
- Lose electrons (oxidised)
- Forming chlorine molecules
- 2Cl- → Cl2 + 2e-
- Chlorine is in group 7 so it is the chloride ions not the hydroxide ions from water that lose electrons)
HIGHER: What happens at the cathode (negative electrode) during electrolysis of aqueous copper chloride?
- Positve copper ions
- Gain electrons (reduced)
- Forming copper atoms
- Cu2+ + 2e- → Cu
- Copper is less reactive than hydrogen, so it is the copper ions that gain electrons.
HIGHER: What happens at the anode (positive electrode) during electrolysis of aqueous sodium sulfate?
- Negative hydroxide ions
- Lose electrons (oxidised)
- Forming water and oxygen molecules
- 4OH- → 2H2O + O2 + 4e-
- Sulfate is not in group 7, so it is the hydroxide ions which lose electrons.
HIGHER: What happens at the cathode (negative electrode) during electrolysis of aqueous sodium sulfate?
- Positve hydrogen ions
- Gain electrons (reduced)
- Forming hydrogen molecules
- 2H+ + 2e- → H2
- Sodium is more reactive than hydrogen, so it is the hydrogen ions that gain electrons.
Triple:
What is oxidised and what is reduced in the following reaction
Hydrochloric acid + iron → iron chloride + hydrogen
2HCl + Fe → FeCl2 + H2
- The iron atoms are oxidised (lose electrons) forming iron ions
- Fe → Fe2+ + 2e-
- The hydrogen ions (from the hydrochloric acid) are reduced (gain electrons) forming hydrogen molecules
- 2H+ + 2e- → H2
Triple:
What is oxidised and what is reduced in the following reaction
Potassium bromide + chlorine → potassium chloride + bromine
2KBr + Cl2 → 2KCl + Br2
2K+ + 2Br- + Cl2→ 2K+ + 2Cl- + Br2
- The bromine ions lose electron (oxidised) forming bromine molecules
- 2Br- → 2Br + 2e-
- The Chlorine molecules gain electrons forming chlorine ions
- Cl2 + 2e- → 2Cl-
Triple:
What is oxidised and what is reduced in the following reaction
Iron + copper sulfate → iron sulfate + copper
Fe + CuSO4 → FeSO4 + Cu
Fe + Cu2+ + SO42- → Fe2+ + SO42- + Cu
- The iron atoms lose electrons (oxidised) forming iron ions
- Fe → Fe2+ + 2e-
- The copper ions gain electrons (reduced) forming copper atoms
- Cu2+ + 2e- → Cu
Triple:
Describe the steps used in a titration to find the concentration of an acid of unknown concentration.
- Use a pipette to add a set volume (25cm3) of the acid to a beaker
- Add a single indicator (e.g litmus) to the acid)
- Fill the burette with an alkali of known concentration
- Add the alkali to the acid a few drops at a time
- Keep adding the alkali until the acid changes colour
- Record the volume of alkali used
- Repeat 3-5 times to calculate an average and identify outliers
Triple:
What is tritration used for
To find the concentration of an acid or alkali of unknown concentration