Chemistry fundamentals Flashcards

1
Q

METRIC units

nano

A

10-9

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2
Q

micro

A

10-4

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3
Q

milli

A

10-3

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4
Q

centi

A

10-2

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5
Q

kilo

A

103

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6
Q

mega

A

106

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7
Q

1000 L =

A

1M3 (1 METER CUBED)

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8
Q

1 L =

A

1000 cm3

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9
Q

angstrom

A

10-10

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10
Q

what is density

A

mass /volume

usually expressed as kg/m3 but also can be in g/cm3 for the mcat know that the density of water is 1 g/cm3

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11
Q

how do we go from g/cm3 to kg/m3

A

multiply by 1000

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12
Q

what is the molecular formula?

A

it gives the identity and number of atoms in the molecule.

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13
Q

what is the empirical formula?

A

smallest whole numbers, it gives the ratio of atoms

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14
Q

common polyatomic atoms that we need to know for the MCAT

A

ammonium NH4+

Hydronium H30+

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15
Q

acetate

A

CH3C02-

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16
Q

BICARBONATE

A

HCO3-

17
Q

CYANIDE

A

CN-

18
Q

HYDROXIDE

A

OH-

19
Q

NITRATE VS NITRITE

A

NO3-
NO2-
ITE = LESS OXGEN

20
Q

PERCHLORATE

A

CL04-

21
Q

CARBONATE

A

CO32-

22
Q

SULFATE VS SULFITE

A

SO42- , SO32- (ITE= LESS OXYGEN)

23
Q

PHOSPHATE

A

PO43-

24
Q

THE MOLE

A
One mole of anything has 6.02 x10^23 entities. 
# moles = mass in grams /molecular weight
25
Q

percent mass composition

A

a molecules emipirical formula can be used to determine the molecules percent mass composition.
we can also use the info about the percent composition to determine the compounds empirical formula.

26
Q

concentration

A

molarity expresses the concentration of a solution in terms of moles of solute per volume in litres

27
Q

what is the mole fraction?

A

fraction of moles of a given substance

- useful when more then 1 solute is present and often used when there are mixed gases

28
Q

law of conservation of mass or matter

A

number of the atoms on the left side of the equation match the number on the right side.

29
Q

Stoichiometric coefficients

A

precede each compound ! tell us in what poportion the reactants react and in what proportion are the products formed. tells us the ratios of the number of molecules ( moles) that apply to the combination of reactants and formation of products.

30
Q

balancing equations

A

start with the most complex species in the reaction

31
Q

what is the limiting reagent ?

A

the reactant we run out of first, it limits how much product the reaction can make. its not necesasarily the reactant that’s initially present in the smallest amount

32
Q

the limiting reagent is always a ?

A

reactant

33
Q

what is a catalyst?

A

substance that increase the rate of the reaction without being consumed.

34
Q

what does the oxidation state or the number tell us?

A

it tells us about the atoms ownership if its valence electrons changes when it forms a compound

35
Q

ionic compounds

A

have complete transfer of electrons.

36
Q

what happens to covalent compounds ?

A

oxidation state of an atom is the charge it would have if the compound were ionic.

37
Q

what are the rules for assigning oxidation?

rem : rule higher in the list will take precedence

A

1) the oxidation state of any element in its standard state is zero
2) the sum of oxidation states of the atoms in a neutral molecule must always be zero and the sum of the oxidation states of the atoms in an ion must always equal the ions charge
3) group 1 metals have a +1 oxidation state and group 2 metals have a +2 oxidation state.
4) fluorine has a -1 oxidation state
5) hydrogen has a +1 oxidation state when bonded to something more electronegative then carbon , but it has a -1 oxidation state when bonded to an atom less electronegative then carbon and a 0 oxidation state when bonded to carbon
6) oxygen has a -2 oxidation state ( exception: in peroxides H202, Na2o2) oxygen has a -1 state bc rule 3 and 5 are higher priority then rule 6.
7) the rest of the halogens have a -1 oxidation state and the atoms of the oxygen family have a -2 oxidation state

38
Q

FONClBrISCH

A

lists elements in order from more electronegative (F) to the least electronegative (H).
so bonds from H to anything NOT found in this list will give H a -1 charge

39
Q

transition metals

A

can have different oxidation states depending on the compound they are in. REM : METAL will never assume a - oxidation state.