Chemistry exam 15.06-16 Flashcards

1
Q

Define azeotropes

A

Anazeotropeor aconstant boiling mixtureis amixtureof two or more liquids whose proportions cannot be altered by simpledistillation.

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2
Q

2 examples of azeotropes

A
  • Positive: Ethanol

- Negative: Hydrochloric acid

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3
Q

Define colligative properties

A

Properties ofsolutionsthat depend on the ratio of the number of solute particles to the number ofsolventmolecules in a solution, and not on the type of chemical species present.

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4
Q

2 examples of colligative properties

A
  • Elevation of boiling point

- Depression of freezing point

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5
Q

Define the third law of thermodynamics

A

Regarding the properties of systems in equilibrium at absolute zero temperature:

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6
Q

Define Avogadro’s law

A

Equal volumes of all gases, at the same temperature and pressure, have the same number of molecules

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7
Q

Wright Van der Waals equation

A

(P+(an^2/v^2) (V-nb)=nRT

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8
Q

Nernst equation for Zn

A

lnQ= ln (conc of reduced component/conc of oxidized component)

lnQ= ln(Zn2+/Zn)

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9
Q

Define internal energy (equation)

A

Inthermodynamics, theinternal energyof asystemis theenergycontained within the system*
∆U ≝ Q + W

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10
Q

Stabilizers of colloids

A
  • electrical charge
  • hydration (solvation)
  • protective colloids
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11
Q

Name a non-ionic surfactant and a cationic surfactant

A

Non-ionic surfactan:

  • fatty alcohols,
  • Cetyl alcohol,
  • Stearyl alcohol,
  • Cetostearyl alcohol
  • Oleyl alcohol.

Cationic surfactant:

  • Bronidox
  • Thonzonium bromide
  • Pahutoxin
  • Olaflur
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12
Q

Define reverse osmosis

A

Reverse osmosis(RO) is a water purification technology that uses asemipermeable membraneto removeions, molecules and larger particles from drinking water.

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13
Q

Define retention factor is TLC

A

Rf= distance traveled by the compound/ distance traveled by the solvent front
0 < Rf < 1

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14
Q

Which is an example of a thickener?

A
Xanthan gum, 
Gum Arabic, 
Gum Tragacanth,
 Guar gum,
 Locus bean gum,
 Gellan gum, 
Sodium Alginate, 
Carrageenans, 
Kappa
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15
Q

Which of the following contains phosphorous: DNA, DDT …

A

DNA

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16
Q

Which has a chiral atom: nicotine, pyrrole…

A

Nicotine

17
Q

Starting unit in terpenes

A

(C5H8)n

18
Q

Central ion of chlorophyll

A

Mg

19
Q

Name 3 mycotoxins

A

Aflatoxins,
Ochratoxins
and Fusarium toxins

20
Q

Name and draw 3 methyl xanthine alkaloids?!

A

Theophylline, Theobromine and Caffeine

21
Q

Name 3 aroma agents

A

Miraculin,
curculin and
L-glutamic acid

22
Q

Write the reaction equation for the formation of any nucleotide

A

Guanine + Ribose + Phosphate = GMP (guaninemonophosphate)

23
Q

Write the dehydration of cholesterol

A
  • OH becomes =O (minus H2O)