Chemistry chapter 7 Flashcards

Need to Know

1
Q

what is E?

A

E is the energy of a photon

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2
Q

what is h and what does it equal?

A

h=6.626x10^-34 J(s), h is planks constant

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3
Q

what are the units of frequency?

A

Hz, s^-1

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4
Q

what is the equation for the energy of a Photon?

A

E=hv

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5
Q

what is the equation of the speed of light?

A

C= wavelength x frequency

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6
Q

what is a quantum?

A

Packet of energy

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7
Q

what is a photon?

A

particle of light

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8
Q

what is wavelength?

A

distance between 2 consecutive peaks or troughs in a wave

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9
Q

what is the principal energy level?

A

It is represented by the principle quantum number n

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10
Q

when wavelength increases, energy and frequency…

A

decreases

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11
Q

wavelength and frequency have a —- type of relationship?

A

inverse

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12
Q

What is the origin of the atomic spectrum?

A

transitions of electrons within an atom as they jump from a higher energy levels to lower energy

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13
Q

What is the continuous spectrum?

A

A continuous spectrum is a range of colors emitted by an object that displays all wavelengths of light without any gaps or interruptions.

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14
Q

what is the quantum model?

A

The electron in a hydrogen atom moves around the nucleus in certain allowed circular orbits

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14
Q

what does the line spectrum show?

A

A line spectrum shows the specific wavelengths of light emitted or absorbed by an element or compound.

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14
Q

energy is ____ and can occur in discrete units of ___

A

quantized; hv

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15
Q

continues spectra shows what number of wavelengths?

A

contains all wavelengths of a given range

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16
Q

how many wavelengths does the line spectrum show?

A

contains only a few wavelengths

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17
Q

radiation from rainbows is an example of what?

A

the continuous spectrum

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18
Q

hydrogen emission spectrum is an example of what?

A

the line spectrum

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19
Q

the line spectrum is aka

A

atomic spectrum

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20
Q

continuous spectrum is aka

A

molecular spetra

21
Q

what is the bohr model?

22
Q

what is the ground state?

A

lowest possible state of an atom or molecule

23
excited state
higher energy state of an atom or molecule can pared to its ground state(when the electron is in any energy level above the ground state)
24
what are some of the important concepts in a bohr model?
Quantized energy levels, stable orbitals, energy transitions, and angular momentum quantization, represent a hydrogen atom model.
25
What is heisenbug's uncertainty principle?
Cannot know both the exact speed (momentum) or position of an electron; if you know one, the other becomes more uncertain.
26
what does an orbital represent?
the probable location of an electron
27
what is an orbit?
refers to the fixed path of an electron that goes around the nucleus
28
what is ψ referring to?
The wave function, coordinates the electrons position in a 3-d space (mathematical description of a quantum state of a particle)
29
What is the Angular momentum quantum number?
l (refers to sublevels)
30
what is the magnetic quantum number
ml
31
What letter represents the size of an orbital?
n
32
what letter represents the shape of an orbital
l (refers to the sublevels)
33
when l=0 what orbital is represented?
s orbital, shape of a sphere
34
when l=1 what orbital is represented?
s, and p orbital (shape of a dumbbell)
35
what is Puli Exclusion Principle?
The Pauli Exclusion Principle states that no two electrons in an atom can have the same set of four quantum numbers. and Electrons have to spin in oposite directions
36
energy sublevels are also known as
orbitals
37
what is the shape of the 2p atomic orbital
dumbbell
38
how many energy sublevels in the 3rd principal energy level?
3
39
The quantum mechanical model of an atom is...
concerned with the probability of finding an electron in a certain position
40
what is the outermost energy level?
valence electrons
41
in order to occupy the same orbital, two electrons must have
opposite spins
42
what are the quanta of light called
Photons
43
What is the light giving off by an electric discharge through a sodium vapor is what?
emission
44
Aufbau Principle
lowest energy fills first
45
Penetration effect
the ability of an electron in an atom to get close to the nucleus, effectively reducing the shielding effect caused by other electrons.(2s electron penetrates too the nucleus more than once in the 2p orbital)
46
square of a wave function
indicates the probability an electron near a particular point in space
47
what are nodes
areas of zero probability in an orbital
48
what is degenerate?
same energy
49
polyelectronic atoms
atoms with more than one electron
50
Hund's rule
how electrons fill degenerate orbitals, each electron will first fill an available orbital individually before any pairing occurs.
51
shielding effect
The shielding effect refers to the phenomenon where inner-shell electrons partially block the attraction between the nucleus and outer-shell electrons.
52
square of a wave function is represented by
probability distribution